Effects of the promoter into the Fe2O3/Al2O3 catalyst on the styrene formation from the dehydrogenation of ethylbenzene in the presence of CO2

被引:0
|
作者
Mimura, N [1 ]
Takahara, I [1 ]
Saito, M [1 ]
Sasaki, Y [1 ]
Murata, K [1 ]
机构
[1] Natl Inst Adv Ind Sci & Technol, AIST, Tsukuba, Ibaraki 3058569, Japan
关键词
ethylbenzene; styrene; dehydrogenation; carbon dioxide;
D O I
暂无
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The effects of the addition of promoter into the Fe2O3/Al2O3 catalyst on the styrene formation from the dehydrogenation of ethylbenzene in the presence Of CO2 were observed. On the addition of alkali earth metal oxides, the order of their effectivenesses were Ba > Sr(equal sign with dot above and below)Ca > none > Mg at initial stage of the reaction (25 min), and, even after 6 hours, the promoting effects of Ba and Sr were observed. As metal oxides other than alkali earth metals, Cr and Zr oxides were also effective.
引用
收藏
页码:332 / 333
页数:2
相关论文
共 50 条
  • [31] MAGNETIC RESONANCE STUDY OF THE Fe2O3/Al2O3 CATALYST IN A CO-N2O REACTION.
    Niwa, Miki
    Yagi, Kunihiko
    Murakami, Yuichi
    1600, (54):
  • [32] The advantage of ceria loading over V2O5/Al2O3 catalyst for vapor phase oxidative dehydrogenation of ethylbenzene to styrene using CO2 as a soft oxidant
    Gurram, Venkata Ramesh Babu
    Enumula, Siva Sankar
    Mutyala, Suresh
    Pochamoni, Ramudu
    Prasad, P. S. Sai
    Burri, David Raju
    Kamaraju, Seetha Rama Rao
    APPLIED PETROCHEMICAL RESEARCH, 2016, 6 (04): : 427 - 437
  • [33] Production of styrene by dehydrogenation of ethylbenzene on a [Re, W]/γ-Al2O3 (K, Ce)/α-Al2O3 porous ceramic catalytic converter
    Fedotov, A. S.
    Uvarov, I.
    Tsodikov, M. V.
    Paul, S.
    Simon, P.
    Marinova, M.
    Dumeignil, F.
    CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2021, 160
  • [34] Oxidative dehydrogenation of ethylbenzene to styrene with carbon dioxide over Fe2O3/TiO2-ZrO2 catalyst:: Influence of chloride
    Reddy, Benjaram M.
    Jin, Hailian
    Han, Dae-Soo
    Park, Sang-Eon
    CATALYSIS LETTERS, 2008, 124 (3-4) : 357 - 363
  • [35] STUDY ON THE MIGRATION OF SULFUR IN COAL COKE BY Fe2O3/γ-Al2O3 CATALYST
    Chen Jihao
    Li Yue
    Zhang Lei
    Xia Fei
    Yang Dongfeng
    Ye Yaneng
    FRESENIUS ENVIRONMENTAL BULLETIN, 2022, 31 (07): : 6851 - 6859
  • [36] Development of stable MoO3/TiO2-Al2O3 catalyst for oxidative dehydrogenation of ethylbenzene to styrene using CO2 as soft oxidant
    Kainthla, Itika
    Babu, Gurram Venkata Ramesh
    Bhanushali, Jayesh T.
    Rao, Kamaraju Seetha Rama
    Nagaraja, Bhari Mallanna
    JOURNAL OF CO2 UTILIZATION, 2017, 18 : 309 - 317
  • [38] Highly efficient nano-sized Fe2O3-K2O catalyst for dehydrogenation of ethylbenzene to styrene
    Xiang Bin
    Xu Hengyong
    Li Wenzhao
    CHINESE JOURNAL OF CATALYSIS, 2007, 28 (10) : 841 - 843
  • [39] Influence of addition of ZnO on property of Fe2O3-K2O system catalyst for ethylbenzene dehydrogenation to styrene
    Miao, CX
    Shan, M
    CHINESE CHEMICAL LETTERS, 2004, 15 (01) : 93 - 96
  • [40] OXIDATION OF HYDROGEN-SULFIDE OVER FE2O3/AL2O3 CATALYST - INFLUENCE OF SUPPORT TEXTURE AND FE2O3 PRECURSOR
    NOVAK, M
    ZDRAZIL, M
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1991, 56 (09) : 1893 - 1899