Facile and economical Miyaura borylation and one-pot Suzuki-Miyaura cross-coupling reaction

被引：9
|
作者：
Boontiem, Phongsakorn [1 ,2 ]
Kiatisevi, Supavadee [1 ,2 ,3 ]
机构：
[1] Mahidol Univ, Fac Sci, Dept Chem, Rama VI Rd, Bangkok 10400, Thailand
[2] Mahidol Univ, Fac Sci, Ctr Excellence Innovat Chem PERCH CIC, Rama VI Rd, Bangkok 10400, Thailand
[3] Mahidol Univ, Fac Sci, Ctr Sustainable Energy & Green Mat, 999 Phuttamonthon Sai 4 Rd, Salaya 73170, Nakhon Pathom, Thailand
来源：
INORGANICA CHIMICA ACTA | 2020年 / 506卷
关键词：
Aryl boronate ester; Miyaura borylation; Suzuki-Miyaura cross-coupling reaction; One-pot reaction; Palladium; CATALYZED BORYLATION; ARYL HALIDES; CHLORIDES; ACCESS;
D O I：
10.1016/j.ica.2020.119538
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Facile and economical method for Miyaura borylation reaction between B(2)pin(2) and aryl bromides is reported. The catalytic system containing 2 mol% PdCl2 (PPh3)(2) and KOAc serves to enable borylations to occur under solvent-free and atmospheric conditions. The developed protocol can be applied to synthesize symmetrical and unsymmetrical biaryls via one-pot two-step Suzuki-Miyaura cross-coupling reaction and also offers the upscalability.
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页数：9
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