Synthesis of Biaryls through a One-Pot Tandem Borylation/Suzuki-Miyaura Cross-Coupling Reaction Catalyzed by a Palladacycle

被引：36

作者：

Wang, Lianhui ^{[1
,2
]}

Cui, Xiuling ^{[1
]}

Li, Jingya ^{[2
]}

Wu, Yusheng ^{[2
]}

Zhu, Zhiwu ^{[1
]}

Wu, Yangjie ^{[1
]}

机构：

[1] Zhengzhou Univ, Henan Univ, Key Lab Appl Chem, Dept Chem,Henan Key Lab Chem Biol & Organ Chem, Zhengzhou 450052, Peoples R China

[2] Tetranov Biopharm Inc, Zhengzhou 450052, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 2012卷 / 03期

基金：

美国国家科学基金会; 中国国家自然科学基金;

关键词：

Cross-coupling; Halides; Borylation; Palladium; Biaryls; C-H BORYLATION; ARYL CHLORIDES; CYCLOPALLADATED FERROCENYLIMINE; SUZUKI; BSC; BROMIDES; CONSTRUCTION; ACTIVATION; AROMATICS; ARYLATION;

D O I：

10.1002/ejoc.201101409

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The tricyclohexylphosphane adduct of cyclopalladated ferrocenylimine I exhibited high catalytic activity in the one-pot borylation/Suzuki-Miyaura coupling (BSC) reaction with low catalyst loading (2 mol-%). Various biaryls were obtained in good to excellent yields for 37 examples. This process was applied to aryl and heteroaryl halides (Br and Cl) containing a variety of functional groups and did not require an excess amount of phosphane ligand and the addition of the palladium catalyst in the second step.

引用

页码：595 / 603

页数：9

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