Mechanism and kinetic studies of inverse microsuspension polymerisation of acrylic acid using water-soluble redox initiators

被引：0
|
作者：
Liu, Z
Brooks, BW
机构：
来源：
1997 JUBILEE RESEARCH EVENT, VOLS 1 AND 2 | 1997年
关键词：
inverse microsuspension polymerisation; acrylic acid; redox initiators; drop mixing;
D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Kinetic studies were conducted for polymerisations of acrylic acid using inverse microsuspension and an aqueous surfactant solution with water-soluble redox initiators under isothermal conditions. A reaction scheme for producing primary radicals was developed. Oxygen can act as an oxidant in radical production. A combination of bimolecular and unimolecular termination mechanism was found. Surfactant molecules probably function as a transfer agent. The drop mixing has a strong effect on overall reaction rate in inverse microsuspension polymerisation.
引用
收藏
页码：1237 / 1240
页数：4
相关论文
共 50 条
  • [41] Studies on dissolution enhancement and mathematical modeling of drug release of a poorly water-soluble drug using water-soluble carriers
    Ahuja, Naveen
    Katare, Om Prakash
    Singh, Bhupinder
    EUROPEAN JOURNAL OF PHARMACEUTICS AND BIOPHARMACEUTICS, 2007, 65 (01) : 26 - 38
  • [42] DETERMINATION OF WEAK ACID RESIDUES IN WATER-SOLUBLE ACRYLAMIDE-ACRYLIC ACID TYPE CO-POLYMERS
    KILMER, NH
    DONARUMA, LG
    HATCH, MJ
    KHUNE, GD
    MARTIN, FD
    SHEPITKA, JS
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1981, 181 (MAR): : 124 - POLY
  • [43] INVESTIGATION OF THE COUPLING OF WATER-SOLUBLE POLY(ACRYLIC ACID) AND POLY(METHACRYLIC ACID) TO AMINES AND TO BETA-GALACTOSIDASE
    BEDDOWS, CG
    BARKER, PS
    GUTHRIE, JT
    POLYMER BULLETIN, 1981, 4 (03) : 149 - 156
  • [44] COUPLING OF ACRYLIC POLYMERS AND COLLAGEN BY USE OF A WATER-SOLUBLE CARBODIIMIDE .2. INVESTIGATIONS OF THE COUPLING MECHANISM
    LLOYD, DR
    BURNS, CM
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1979, 17 (11) : 3473 - 3483
  • [45] ELECTROCATALYSIS OF OXYGEN REDUCTION BY WATER-SOLUBLE IRON PORPHYRINS - THERMODYNAMIC AND KINETIC ADVANTAGE STUDIES
    SU, YO
    KUWANA, T
    CHEN, SM
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 288 (1-2) : 177 - 195
  • [46] Enzymatic synthesis and characterization of an water-soluble conducting poly (1, 4-diaminobenzene-acrylic acid)
    Zeng, Jiayu
    Zhang, Weibo
    Liao, Shiqi
    Zhang, Dongxia
    Wang, Yunpu
    Wang, Yuxian
    Liu, Furong
    MANUFACTURING PROCESSES AND SYSTEMS, PTS 1-2, 2011, 148-149 : 118 - +
  • [47] Water-soluble starlike poly(acrylic acid) graft polymer: preparation and application as templates for silver nanoclusters
    Huiqiang Li
    Zhanxian Li
    Linzhi Wu
    Fang Liu
    Jie Zhou
    Miao Luan
    Mingming Yu
    Liuhe Wei
    Polymer Bulletin, 2012, 68 : 2229 - 2242
  • [48] Water-Soluble Hybrid Core–Shell Nanoparticles with Titanium Dioxide Core and Poly(Acrylic Acid) Shell
    E. L. Krasnopeeva
    G. G. Panova
    S. G. Laishevkina
    E. Yu. Melenevskaya
    N. V. Zakharova
    E. N. Vlasova
    A. V. Yakimansky
    Polymer Science, Series B, 2023, 65 : 974 - 979
  • [49] Water-soluble nanospheres of poly(2-cinnamoylethyl methacrylate)-block-poly(acrylic acid)
    Henselwood, F
    Liu, GJ
    MACROMOLECULES, 1997, 30 (03) : 488 - 493
  • [50] Water-soluble starlike poly(acrylic acid) graft polymer: preparation and application as templates for silver nanoclusters
    Li, Huiqiang
    Li, Zhanxian
    Wu, Linzhi
    Liu, Fang
    Zhou, Jie
    Luan, Miao
    Yu, Mingming
    Wei, Liuhe
    POLYMER BULLETIN, 2012, 68 (09) : 2229 - 2242
12345