Mechanism and kinetic studies of inverse microsuspension polymerisation of acrylic acid using water-soluble redox initiators

被引：0
|
作者：
Liu, Z
Brooks, BW
机构：
来源：
1997 JUBILEE RESEARCH EVENT, VOLS 1 AND 2 | 1997年
关键词：
inverse microsuspension polymerisation; acrylic acid; redox initiators; drop mixing;
D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Kinetic studies were conducted for polymerisations of acrylic acid using inverse microsuspension and an aqueous surfactant solution with water-soluble redox initiators under isothermal conditions. A reaction scheme for producing primary radicals was developed. Oxygen can act as an oxidant in radical production. A combination of bimolecular and unimolecular termination mechanism was found. Surfactant molecules probably function as a transfer agent. The drop mixing has a strong effect on overall reaction rate in inverse microsuspension polymerisation.
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页码：1237 / 1240
页数：4
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