Hybrid molecular materials based on covalently linked inorganic polyoxometalates and organic conjugated systems

被引：1

作者：

Xu, BB

Wei, YG

Barnes, CL

Peng, ZH ^{[1
]}

机构：

[1] Univ Missouri, Dept Chem, Kansas City, MO 64110 USA

[2] Univ Missouri, Dept Chem, Elmer O Schlemper Xray Diffract Ctr, Columbia, MO 65211 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2001年 / 40卷 / 12期

关键词：

molybdenum; organic-inorganic hybrids; palladium; polyoxometalates;

D O I：

10.1002/1521-3773(20010618)40:12<2290::AID-ANIE2290>3.0.CO;2-P

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Mo≡N bond is conjugated with the organic segment in the novel molecular organic-inorganic hybrid materials that have been obtained by Pd-catalyzed coupling of an iodo-functionalized hexamolybdate anion and an alkyne (see scheme; Ar = 4-methylphenyl, 3-5-di(tert-butyl)phenyl). The interaction between the polyoxometalate cluster and the organic conjugated system is particularly apparent from the strong red-shifted absorption in the UV/Vis spectrum.

引用

页码：2290 / +

页数：4

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