Hybrid molecular materials based on covalently linked inorganic polyoxometalates and organic conjugated systems

被引：2
|
作者：
Xu, BB
Wei, YG
Barnes, CL
Peng, ZH [1 ]
机构：
[1] Univ Missouri, Dept Chem, Kansas City, MO 64110 USA
[2] Univ Missouri, Dept Chem, Elmer O Schlemper Xray Diffract Ctr, Columbia, MO 65211 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2001年 / 40卷 / 12期
关键词：
molybdenum; organic-inorganic hybrids; palladium; polyoxometalates;
D O I：
10.1002/1521-3773(20010618)40:12<2290::AID-ANIE2290>3.0.CO;2-P
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Mo≡N bond is conjugated with the organic segment in the novel molecular organic-inorganic hybrid materials that have been obtained by Pd-catalyzed coupling of an iodo-functionalized hexamolybdate anion and an alkyne (see scheme; Ar = 4-methylphenyl, 3-5-di(tert-butyl)phenyl). The interaction between the polyoxometalate cluster and the organic conjugated system is particularly apparent from the strong red-shifted absorption in the UV/Vis spectrum.
引用
收藏
页码：2290 / +
页数：4
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