Self-organized porous and tubular oxide layers on TiAl alloys

The present paper describes the electrochemical fabrication of nanostructured oxide films on a TiAl intermetallic compound. The alloy is investigated under conditions where the individual alloying elements show the growth of ordered oxide structures, i.e. anodization is carried out in fluoride containing and fluoride free H2SO4 electrolytes. In 1 M H2SO4 the alloy shows randomly ordered nanoporous oxide structures while in HF-containing electrolytes highly ordered films can be formed. The key factor that affects the morphology is the anodizing potential. At low potentials (similar to 10 V) self-organized nanopores are formed whereas at higher potentials (similar to 40 V) separation of the pore walls and therefore formation of nanotubes can be observed. The results clearly indicate that on TiAl a wide range of nanoscale morphologies can be achieved ranging from random porous to organized pores to organized tubes. (c) 2007 Elsevier B.V. All rights reserved.