A mixed-valence coordination polymer featuring two-dimensional ferroelectric order:: {[CuI4CuII(Et2dtc)2Cl3][CuII(Et2dtc)2]2(FeC4)}n (Et2dtc- = diethyidithiocarbamate)

被引：117
|
作者：
Okubo, T
Kawajiri, R
Mitani, T
Shimoda, T
机构：
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Nomi, Ishikawa 9231292, Japan
[2] SEIKO EPSON Corp, Technol Platform Res Ctr, Nagano, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 50期
关键词：
D O I：
10.1021/ja056030p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first mixed-valence coordination polymer indicating ferroelectric properties, {[CuI4CuII(Et2dtc)2Cl3][CuII(Et2dtc)2]2(FeCl4)}n (Et2dtc- = diethyldithiocarbamate), has been synthesized and crystallographically characterized. This complex has a two-dimensional infinite square lattice structure, including both Cu(I) and Cu(II) ions, which is confirmed by XPS and SQUID measurements. In addition, the ferroelectric behaviors are revealed by the dielectric measurements with a LCR meter and a ferroelectric tester. Copyright © 2005 American Chemical Society.
引用
收藏
页码：17598 / 17599
页数：2
相关论文
共 50 条
  • [41] PREPARATION AND ELECTROCHEMICAL BEHAVIOR OF TRIS DITHIOCARBAMATO COMPLEXES [BU4N]M(ET2DTC)3 WITH M=BA, ZN, CD, AND HG
    NIEUWPOORT, A
    DIX, AH
    PORSKAMP, PATW
    VANDERLINDEN, JGM
    INORGANICA CHIMICA ACTA, 1979, 35 (02) : 221 - 226
  • [42] Synthesis and structural characterization of a linear copper(I) tetrathiomolybdate complex containing the Me(2)dtc(-) ligand, (Et4N)(2)[MoS4(CuMe(2)dtc)(2)]
    Zhu, HP
    Huang, XY
    Deng, YH
    Wu, DX
    Chen, CN
    Liu, QT
    INORGANICA CHIMICA ACTA, 1997, 256 (01) : 29 - 34
  • [43] CRYSTAL AND MOLECULAR-STRUCTURE OF THE NOVEL MIXED-VALENCE COMPLEX MU-BIS(N,N-DIETHYLDITHIOCARBAMATO)-BIS(N,N-DIETHYLDITHIOCARBAMATO)-DICARBONYLDIRUTHENIUM(II,III) TETRAFLUOROBORATE, [RU2(ET2DTC)4(CO)2]BF4
    PIGNOLET, LH
    WHEELER, SH
    INORGANIC CHEMISTRY, 1980, 19 (04) : 935 - 940
  • [44] Synthesis and Structure of a 〔Mo3S7〕3.5+ Complex〔Mo3（μ3-S）(μ2-S2)3（Et2dtc）3〕2Cl
    ZHU Hong-Ping
    LIU Qiu-Tian
    CHEN Chang-Neng
    DENG Yu-Heng(State Key Laboratory of Structural Chemistry
    结构化学, 1998, (02) : 142 - 146
  • [45] SYNTHESIS, CRYSTAL-STRUCTURE AND PROPERTIES OF THE SPIN SINGLET 6-COORDINATED NI(II) COMPOUND NI(ET2DTC)2(ASI3)2
    WILLEMSE, J
    CRAS, JA
    BOSMAN, WP
    STEGGERDA, JJ
    RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1980, 99 (02): : 65 - 67
  • [46] Synthesis and Crystal Structure of a Three-Dimensional Mixed-Valence Copper Dithiocarbamate-Copper Iodide Coordination Polymer [Cu(Me2dtc)2(CuI)3]n
    Fan Le-Qing
    Wu Ji-Huai
    Lin Jian-Ming
    Huang Yun-Fang
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2010, 26 (08) : 1516 - 1520
  • [47] LIGAND SUBSTITUTION AT A HEXA-COORDINATE CENTER .4. A KINETIC-STUDY OF THE REACTION OF [CO2(ET2DTC)5]BF4 WITH SOME ETHYLENEDIAMINES
    DEPLANO, P
    TROGU, EF
    INORGANICA CHIMICA ACTA-ARTICLES, 1983, 68 (JAN): : 153 - 156
  • [48] Determination of constant-volume combustion energies for complexes of RE(Et2dtC)3(phen) (RE=La, Pr, Nd, Sm)
    Zhu, L
    Yang, XW
    Chen, SP
    Gao, SL
    Shi, QZ
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2004, 20 (11) : 1303 - 1308
  • [49] MoFe3S4单立方烷自兜合成及（Et4N）(MoFe3S（Et2dtc）5]·MeCN的晶体结构
    刘秋田
    黄梁仁
    王玲玲
    康北笙
    卢嘉锡
    结构化学, 1983, (04) : 291 - 293
  • [50] RE（Et2dtc）3（phen）(RE=La,Pr,Nd,Sm)的恒容燃烧能测定（英文）
    朱丽
    杨旭武
    陈三平
    高胜利
    史启祯
    无机化学学报, 2004, (11) : 1303 - 1308+1243
12345