A mixed-valence coordination polymer featuring two-dimensional ferroelectric order:: {[CuI4CuII(Et2dtc)2Cl3][CuII(Et2dtc)2]2(FeC4)}n (Et2dtc- = diethyidithiocarbamate)

被引：117
|
作者：
Okubo, T
Kawajiri, R
Mitani, T
Shimoda, T
机构：
[1] Japan Adv Inst Sci & Technol, Sch Mat Sci, Nomi, Ishikawa 9231292, Japan
[2] SEIKO EPSON Corp, Technol Platform Res Ctr, Nagano, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 50期
关键词：
D O I：
10.1021/ja056030p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The first mixed-valence coordination polymer indicating ferroelectric properties, {[CuI4CuII(Et2dtc)2Cl3][CuII(Et2dtc)2]2(FeCl4)}n (Et2dtc- = diethyldithiocarbamate), has been synthesized and crystallographically characterized. This complex has a two-dimensional infinite square lattice structure, including both Cu(I) and Cu(II) ions, which is confirmed by XPS and SQUID measurements. In addition, the ferroelectric behaviors are revealed by the dielectric measurements with a LCR meter and a ferroelectric tester. Copyright © 2005 American Chemical Society.
引用
收藏
页码：17598 / 17599
页数：2
相关论文
共 50 条
  • [31] Determination of combustion energies and the standard enthalpies of formation for the complexes of RE(Et2dtc)3(phen)
    Yang, XW
    Zhu, L
    Chen, SP
    Gao, SL
    Shi, QZ
    SCIENCE IN CHINA SERIES B-CHEMISTRY, 2005, 48 (Suppl 1): : 88 - 92
  • [32] Standard enthalpies of formation of RE(Et2dtc)3(phen) (RE = Sm, Eu, and Gd)
    Chen, S
    Gao, S
    Wei, Q
    Xie, G
    Shi, Q
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 2005, 79 (07): : 1022 - 1028
  • [33] Mixed-ligand complexes of rhenium .9. Reactions on the nitrido ligand of [ReN(Me(2)PhP)(Et(2)dtc)(2)]. Synthesis, characterization, and structures of [Re(NBCl3)(Me(2)PhP)(Et(2)dtc)(2)], [Re(NGaCl3)(Me(2)PhP)(Et(2)dtc)(2)], and [Re(NS)Cl(Me(2)PhP)(2)(Et(2)dtc)]
    Ritter, S
    Abram, U
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (06): : 965 - 973
  • [34] [Re{NB(C6F5)3}(Et2dtc)2]2 -: Dimerization as a consequence of the formation of a nitrido bridge
    Abram, U
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1999, 625 (06): : 839 - 841
  • [35] PREPARATION OF BINUCLEAR S,S BRIDGED MOLYBDENUM(V) COMPLEXES CRYSTAL AND MOLECULAR-STRUCTURE OF [MO2S4(ET2DTC)2]
    MULLER, A
    BHATTACHARYYA, RG
    MOHAN, N
    PFEFFERKORN, B
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1979, 454 (07): : 118 - 124
  • [36] Syntheses, structures, and magnetic properties of Di-μ3-chloride-bridged tripalladium compounds, [Pd3(μ3-Cl)2 (HqnS)6]Cl2 (HqnS = Quinoline-2(1H)-thione) and [Pd3(μ3-Cl)2(Et2dtc)2(PPh3)2]•C6H6 (Et2dtc = N, N′-diethyldithiocarbamate)
    Sugimoto, K
    Kuroda-Sowa, T
    Goto, T
    Maekawa, M
    Munakata, M
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (03) : 651 - 655
  • [37] 类立方烷簇（Et4N）[MoFe3S4（Et2dtc）5]CH3CH的质谱
    蔡元坝
    戴亮
    刘秋田
    张易宁
    陈宏琳
    结构化学, 1986, (04) : 247 - 255
  • [38] Electronic Structures of [RuII(cyclam)(Et2dtc)]+, [Ru(cyclam)(tdt)]+, and [Ru(cyclam)(tdt)]2+ : An X-ray Absorption Spectroscopic and Computational Study (tdt = toluene-3,4-dithiolate; Et2dtc = N,N-diethyldithiocarbamate(1-))
    Milsmann, Carsten
    Bill, Eckhard
    Weyhermueller, Thomas
    George, Serena DeBeer
    Wieghardt, Karl
    INORGANIC CHEMISTRY, 2009, 48 (20) : 9754 - 9766
  • [39] [Re(NBH2SBH3)(Me2PhP)(Et2dtc)]2 -: a novel rhenium dimer with the unusual bridging (NBH2SBH3)4- ligand
    Abram, U
    INORGANIC CHEMISTRY COMMUNICATIONS, 1999, 2 (06) : 227 - 229
  • [40] Trinuclear vanadium dialkyldithiocarbamate complexes.: Synthesis, structure and spectroscopic characterization of [Et4N][V3(μ3-S)(η2-μ-S2)3(Et2dtc)3]•2CH3CN
    Zhu, HP
    Liu, QT
    Deng, YH
    Wen, TB
    Chen, CN
    Wu, DX
    INORGANICA CHIMICA ACTA, 1999, 286 (01) : 7 - 13
12345