Metal-Free, Radical Addition to Alkenes via Desulfitative Chlorine Atom Transfer

被引：19
|
作者：
Cao, Lidong [1 ]
Weidner, Karin [1 ]
Renaud, Philippe [1 ]
机构：
[1] Univ Bern, Dept Chem & Biochem, CH-3012 Bern, Switzerland
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 18期
基金：
瑞士国家科学基金会;
关键词：
amides; atom-transfer radical addition (ATRA) reaction; chlorine atom transfer; desulfitation; esters; radical reaction; sulfonyl chloride; trichloromethyl radical; TRANSFER CYCLIZATION REACTIONS; ALPHA-IODO ESTERS; RUTHENIUM(II) COMPLEX; COORDINATION SPHERE; ASYMMETRIC ADDITION; SULFONYL CHLORIDE; KHARASCH REACTION; ALKYL RADICALS; ATRC REACTIONS; RATE CONSTANTS;
D O I：
10.1002/adsc.201100473
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
An efficient method for radical additions to unactivated alkenes via desulfitative chlorine-atom transfer is described. The reaction is based on the use of readily available sulfonyl chlorides as starting materials and cheap radical initiators such as azobisisobutyronitrile (AIBN), di-tert-butyldiazene (DTBD), and dilauroyl peroxide (DLP). No transition metal catalyst is required and the reaction takes place under mild conditions at temperatures <= 85 degrees C.
引用
收藏
页码：3467 / 3472
页数：6
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