A Highly Versatile Catalytic System for N-Arylation of Amines with Aryl Chlorides in Water

被引：27

作者：

Huang, Manna ^{[1
]}

Lin, Xiaoqin ^{[1
]}

Zhu, Xinhai ^{[1
]}

Peng, Weili ^{[1
]}

Xie, Jianwei ^{[1
]}

Wan, Yiqian ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 24期

基金：

中国国家自然科学基金; 国家高技术研究发展计划(863计划);

关键词：

Copper; Cross-coupling; Amination; Water chemistry; EFFICIENT COPPER CATALYST; HETEROATOM BOND FORMATION; CROSS-COUPLING REACTIONS; C-N; HALIDES; AMINATION; ULLMANN; PALLADIUM; LIGANDS; IODIDES;

D O I：

10.1002/ejoc.201100458

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The C-N coupling between nucleophiles and aryl chlorides, which are less expensive, less reactive, and more abundant than their bromide and iodide counterparts, is challenging but of great interest for industrial applications. An oxalyldihydrazide/hexane-2,5-dione (100-150 mol-%)/CuO system was found to enable the reaction of a wide range of nucleophiles with a variety of aryl chlorides in water for the first time.

引用

页码：4523 / 4527

页数：5

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