N-Arylation of Amines with o-Silylaryl Triflate

被引：1
|
作者：
Lee, Y. G. [1 ]
Jung, D. I. [1 ]
Hahn, J. T. [2 ]
机构：
[1] Dong A Univ, Dept Chem, Pusan 604714, South Korea
[2] Youngdong Univ, Dept Beautycare, Youngdong 370701, South Korea
来源：
ASIAN JOURNAL OF CHEMISTRY | 2013年 / 25卷 / 12期
关键词：
N-Arylation; o-Silylaryl triflate; CsF; Amines; PALLADIUM-CATALYZED AMINATION; COUPLING REACTION; STRAIGHTFORWARD SYNTHESIS; EFFICIENT CATALYST; ARYL CHLORIDES; BOND; BROMIDES; ACCEPTOR; IODIDES; COMPLEX;
D O I：
10.14233/ajchem.2013.14423
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient, transition-metal-free procedure for the N-arylation of amines 1 has been achieved by allowing those substrates to react with o-silylaryl triflate 2 in the presence of CsF. Good to excellent yields of arylated products 3 are obtained under very mild reaction conditions. This chemistry readily tolerates a variety of functional groups.
引用
收藏
页码：6690 / 6692
页数：3
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