A novel palladium-catalyzed coupling of thiol esters with 1-alkynes

被引：0
|
作者：
Tokuyama, H [1 ]
Miyazaki, T [1 ]
Yokoshima, S [1 ]
Fukuyama, T [1 ]
机构：
[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Bunkyo Ku, Tokyo 1130033, Japan
来源：
SYNLETT | 2003年 / 10期
关键词：
1-alkynyl ketones; thiol esters; Sonogashira-type coupling reaction; palladium; copper;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new method for synthesizing alpha,beta-acetylenic ketones by palladium-mediated coupling of thiol esters with I -alkynes is described. The reaction could be applied to coupling of thiol esters bearing various functional groups, such as aromatic bromides, and ketones, with functionalized terminal acetylenes.
引用
收藏
页码：1512 / 1514
页数：3
相关论文
共 50 条
  • [31] Palladium-Catalyzed Suzuki-Miyaura Coupling of Aryl Esters
    Ben Halima, Taoufik
    Zhang, Wanying
    Yalaoui, Imane
    Hong, Xin
    Yang, Yun-Fang
    Houk, Kendall N.
    Newman, Stephen G.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (03) : 1311 - 1318
  • [32] Divergent Palladium-Catalyzed Cross-Coupling of Nitropyrazoles with Terminal Alkynes
    Ha, Hyeri
    Shin, Changhoon
    Bae, Seri
    Joo, Jung Min
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 2018 (20-21) : 2645 - 2650
  • [33] Cationic palladium-catalyzed hydrosilylative cross-coupling of alkynes with alkenes
    Shimamoto, T
    Chimori, M
    Sogawa, H
    Yamamoto, K
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (47) : 16410 - 16411
  • [34] Palladium-catalyzed carbonylative Sonogashira coupling between aryl triazenes and alkynes
    Li, Wanfang
    Wu, Xiao-Feng
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2015, 13 (18) : 5090 - 5093
  • [35] Palladium-catalyzed dehydrogenative coupling of terminal alkynes with secondary phosphine oxides
    Yang, Jia
    Chen, Tieqiao
    Zhou, Yongbo
    Yin, Shuangfeng
    Han, Li-Biao
    CHEMICAL COMMUNICATIONS, 2015, 51 (17) : 3549 - 3551
  • [36] Palladium-catalyzed Sonogashira cross-coupling of organic tellurides with alkynes
    Kawaguchi, Shin-ichi
    Srivastava, Puneet
    Engman, Lars
    TETRAHEDRON LETTERS, 2011, 52 (32) : 4120 - 4122
  • [37] THE PALLADIUM-CATALYZED CARBONYLATIVE COUPLING OF 5-(TRIMETHYLSILYLETHYNYL)-3',5'-DI-O-ACETYL-2' DEOXYURIDINE AND 1-ALKYNES WITH ARYL IODIDES
    ARCADI, A
    CACCHI, S
    MARINELLI, F
    PACE, P
    SANZI, G
    SYNLETT, 1995, (08) : 823 - 824
  • [38] Ruthenium-catalyzed hydrosilylation of 1-alkynes with novel regioselectivity
    Kawanami, Y
    Sonoda, Y
    Mori, T
    Yamamoto, K
    ORGANIC LETTERS, 2002, 4 (17) : 2825 - 2827
  • [39] Palladium-catalyzed addition of tetragermetanes to alkynes
    Mochida, K
    Hirahue, K
    Suzuki, K
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2003, 76 (05) : 1023 - 1028
  • [40] Palladium-catalyzed additions of terminal alkynes to acceptor alkynes
    Trost, BM
    Sorum, MT
    Chan, C
    Harms, AE
    Ruhter, G
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (04) : 698 - 708
12345