The modulation of face-face π-π interactions in Lewis acid catalysis

被引：4
|
作者：
Harris, LD [1 ]
Jenkins, RL [1 ]
Tomkinson, NCO [1 ]
机构：
[1] Cardiff Univ, Sch Chem, Cardiff CF10 3TB, S Glam, Wales
来源：
TETRAHEDRON LETTERS | 2005年 / 46卷 / 10期
基金：
英国工程与自然科学研究理事会;
关键词：
Lewis acids; Diels-Alder reaction; pi-pi interactions;
D O I：
10.1016/j.tetlet.2005.01.086
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The enantiomeric excess observed for the exo-adduct from the Lewis acid catalysed Diels-Alder reaction between cyclopentadiene and niethacrolein can be increased Lip to 21%, by simple modification of the electronics of the aromatic ring in a series of stilbene-derived diol ligands, suggesting that the proposed face-face pi-pi interaction between the catalyst and the dienophile can be modulated by altering the electron density on the aromatic ring. (C) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1627 / 1629
页数：3
相关论文
共 50 条
  • [41] Getting to know you: Face-to-face versus online interactions
    Okdie, Bradley M.
    Guadagno, Rosanna E.
    Bernieri, Frank J.
    Geers, Andrew L.
    Mclarney-Vesotski, Amber R.
    COMPUTERS IN HUMAN BEHAVIOR, 2011, 27 (01) : 153 - 159
  • [42] The Architecture of Innovation: Tracking Face-to-Face Interactions with UbiComp Technologies
    Brown, Chloe
    Efstratiou, Christos
    Leontiadis, Ilias
    Quercia, Daniele
    Mascolo, Cecilia
    Scott, James
    Key, Peter
    UBICOMP'14: PROCEEDINGS OF THE 2014 ACM INTERNATIONAL JOINT CONFERENCE ON PERVASIVE AND UBIQUITOUS COMPUTING, 2014, : 811 - 822
  • [43] Understanding the Impact of Personal Feedback on Face-to-Face Interactions in the Workplace
    Mashhadi, Afra
    Mathur, Akhil
    Van den Broeck, Marc
    Vanderhulst, Geert
    Kawsar, Fahim
    ICMI'16: PROCEEDINGS OF THE 18TH ACM INTERNATIONAL CONFERENCE ON MULTIMODAL INTERACTION, 2016, : 362 - 369
  • [44] Judging the credibility of information gathered from face-to-face interactions
    Jensen M.L.
    Burgoon J.K.
    Nunamaker Jr. J.F.
    Journal of Data and Information Quality, 2010, 2 (01)
  • [45] Face to Face, Brain to Brain: Exploring the Mechanisms of Dyadic Social Interactions
    Hasson, Uri
    INTERNATIONAL JOURNAL OF PSYCHOLOGY, 2016, 51 : 873 - 874
  • [46] COMPARATIVE ANALYSIS ABOUT FACE TO FACE AND VIRTUAL INTERACTIONS OF SECONDARY STUDENTS
    Sanchez Vera, Maria del Mar
    Serrano Sanchez, Jose Luis
    Prendes Espinosa, Maria Paz
    EDUCACION XX1, 2013, 16 (01): : 351 - 374
  • [47] Saving face in diplomacy: A political sociology of face-to-face interactions in the Association of Southeast Asian Nations
    Nair, Deepak
    EUROPEAN JOURNAL OF INTERNATIONAL RELATIONS, 2019, 25 (03) : 672 - 697
  • [48] Knowledge diffusion dynamics and network properties of face-to-face interactions
    Piergiuseppe Morone
    Richard Taylor
    Journal of Evolutionary Economics, 2004, 14 : 327 - 351
  • [49] MOTHER-INFANT FACE-TO-FACE INTERACTIONS AND THE ORGANIZATION OF ATTENTION
    SCHLANSKER, JT
    JOURNAL OF GENETIC PSYCHOLOGY, 1982, 140 (01): : 153 - 154
  • [50] A Case Study on Capturing and Visualising Face-to-Face Interactions in the Workplace
    Mashhadi, Afra
    Mathur, Akhil
    Van den Broeck, Marc
    Vanderhulst, Geert
    Godon, Marc
    Kawsar, Fahim
    PROCEEDINGS OF THE 18TH INTERNATIONAL CONFERENCE ON HUMAN-COMPUTER INTERACTION WITH MOBILE DEVICES AND SERVICES (MOBILEHCI 2016), 2016, : 575 - 584
12345