Aroylation of aromatics with arylcarboxylic acids over Nafion-H (polymeric perfluoroalkanesulfonic acid), an environmentally friendly solid acid catalyst

被引：15

作者：

Prakash, GKS ^{[1
]}

Mathew, T

Mandal, M

Farnia, M

Olah, GA

机构：

[1] Univ So Calif, Loker Hydrocarbon Res Inst, Los Angeles, CA 90089 USA

[2] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA

来源：

ARKIVOC | 2004年

关键词：

Nafion-H; Friedel-Crafts aroylation; benzophenones; ionic liquids; trifluoromethylated alcohols;

D O I：

10.3998/ark.5550190.0005.812

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aromatic hydrocarbons undergo direct aroylation with arylcarboxylic acids over Nafion-H, an environmentally friendly, perfluorinated resinsulfonic acid catalyst to give benzophenones and their derivatives. Furthermore, one of the bistrifluoromethylated benzophenone derivative was trifluoromethylated to a new DDT analog.

引用

页码：103 / 110

页数：8

共 50 条

[41] Biomass derived β-cyclodextrin-SO3H as a solid acid catalyst for esterification of carboxylic acids with alcohols
Thombal, Raju S.
Jadhav, Amol R.
Jadhav, Vrushali H.
RSC ADVANCES, 2015, 5 (17): : 12981 - 12986
[42] SnF2-catalyzed glycerol ketalization: A friendly environmentally process to synthesize solketal at room temperature over on solid and reusable Lewis acid
da Silva, Márcio José
de Ávila Rodrigues, Fabio
Júlio, Armanda Aparecida
Chemical Engineering Journal, 2017, 307 : 828 - 835
[43] SOLID SUPERACID-CATALYZED ORGANIC-SYNTHESIS .4. PERFLUORINATED RESINSULFONIC ACID (NAFION-H) CATALYZED FRIEDEL-CRAFTS BENZYLATION OF BENZENE AND SUBSTITUTED BENZENES
YAMATO, T
HIDESHIMA, C
PRAKASH, GKS
OLAH, GA
JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (06): : 2089 - 2091
[44] SnF2-catalyzed glycerol ketalization: A friendly environmentally process to synthesize solketal at room temperature over on solid and reusable Lewis acid
da Silva, Marcio Jose
Rodrigues, Fabio de Avila
Julio, Armanda Aparecida
CHEMICAL ENGINEERING JOURNAL, 2017, 307 : 828 - 835
[45] HETEROGENEOUS CATALYSIS BY SOLID SUPERACIDS .13. PERFLUORINATED RESINSULFONIC ACID (NAFION-H) CATALYZED INTER INTER-MOLECULAR AND INTRA-MOLECULAR ISOMERIZATION (TRANSBROMINATION) OF BROMOAROMATIC COMPOUNDS
OLAH, GA
MEIDAR, D
OLAH, JA
NOUVEAU JOURNAL DE CHIMIE-NEW JOURNAL OF CHEMISTRY, 1979, 3 (04): : 275 - 277
[46] ORGANIC-REACTIONS CATALYZED BY SOLID SUPERACIDS .9. FRIEDEL CRAFTS CYCLOBENZYLATION OF BENZENE WITH BIS(HYDROXYMETHYL)DIARYLALKANES CATALYZED BY A PERFLUORINATED SULFONIC-ACID RESIN (NAFION-H)
YAMATO, T
SAKAUE, N
FURUSAWA, T
TASHIRO, M
PRAKASH, GKS
OLAH, GA
JOURNAL OF CHEMICAL RESEARCH-S, 1991, (09): : 242 - 243
[47] SYNTHETIC METHODS AND REACTIONS .51. CONVENIENT AND IMPROVED METHOD FOR ESTERIFICATION OVER NAFION-H2, A SUPERACIDIC PERFLUORINATED RESINSULFONIC ACID CATALYST
OLAH, GA
KEUMI, T
MEIDAR, D
SYNTHESIS-STUTTGART, 1978, (12): : 929 - 930
[48] SYNTHETIC METHODS AND REACTIONS .98. IMPROVED SOLID SUPER ACID (NAFION-H) CATALYZED RUPE REARRANGEMENT OF ALPHA-ETHYNYL ALCOHOLS TO ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS
OLAH, GA
FUNG, AP
SYNTHESIS-STUTTGART, 1981, (06): : 473 - 474
[49] SOLID SUPERACID CATALYZED ORGANIC-SYNTHESIS .6. PERFLUORINATED RESINSULFONIC ACID (NAFION-H) CATALYZED RING-CLOSURE REACTION OF 2,2'-DIHYDROXYBIPHENYLS - A PREPARATIVE ROUTE TO DIBENZOFURANS
YAMATO, T
HIDESHIMA, C
PRAKASH, GKS
OLAH, GA
JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (09): : 3192 - 3194
[50] Synthesis of substituted coumarins catalyzed by sawdust-SO3H. An efficient and environmentally benign solid acid catalyst under solvent-free conditions
Tahanpesar, E.
Sarami, L.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2015, 85 (09) : 2135 - 2140

← 1 2 3 4 5 →