Aroylation of aromatics with arylcarboxylic acids over Nafion-H (polymeric perfluoroalkanesulfonic acid), an environmentally friendly solid acid catalyst

被引：15

作者：

Prakash, GKS ^{[1
]}

Mathew, T

Mandal, M

Farnia, M

Olah, GA

机构：

[1] Univ So Calif, Loker Hydrocarbon Res Inst, Los Angeles, CA 90089 USA

[2] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA

来源：

ARKIVOC | 2004年

关键词：

Nafion-H; Friedel-Crafts aroylation; benzophenones; ionic liquids; trifluoromethylated alcohols;

D O I：

10.3998/ark.5550190.0005.812

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aromatic hydrocarbons undergo direct aroylation with arylcarboxylic acids over Nafion-H, an environmentally friendly, perfluorinated resinsulfonic acid catalyst to give benzophenones and their derivatives. Furthermore, one of the bistrifluoromethylated benzophenone derivative was trifluoromethylated to a new DDT analog.

引用

页码：103 / 110

页数：8

共 50 条

[21] SYNTHETIC METHODS AND REACTIONS .99. PREPARATION OF CYCLIC ETHERS OVER SUPERACIDIC PERFLUORINATED RESINSULFONIC ACID (NAFION-H) CATALYST
OLAH, GA
FUNG, AP
MALHOTRA, R
SYNTHESIS-STUTTGART, 1981, (06): : 474 - 476
[22] PROTON NMR METHOD FOR THE QUANTITATIVE-DETERMINATION OF THE WATER-CONTENT OF THE POLYMERIC FLUOROSULFONIC ACID NAFION-H
BUNCE, NJ
SONDHEIMER, SJ
FYFE, CA
MACROMOLECULES, 1986, 19 (02) : 333 - 339
[23] HETEROGENEOUS CATALYSIS BY SOLID SUPERACIDS .4. METHYLATION OF PHENOLS WITH METHYL-ALCOHOL AND REARRANGEMENT OF ANISOLE AND METHYLANISOLES OVER A PERFLUORINATED RESINSULFONIC ACID (NAFION-H) CATALYST
KASPI, J
OLAH, GA
JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (16): : 3142 - 3147
[24] Perfluorinated resin-sulfonic acid ( Nafion-H):: an efficient, environment friendly and recyclable heterogeneous catalyst for the one-pot multicomponent synthesis of β-acetamido ketones
Yakaiah, T.
Lingaiah, B. P. V.
Reddy, G. Venkat
Narsaiah, B.
Rao, P. Shanthan
ARKIVOC, 2007, : 227 - 234
[25] HETEROGENEOUS CATALYSIS BY SOLID SUPERACIDS .17. POLYMERIC PERFLUORINATED RESIN SULFONIC-ACID (NAFION-H) CATALYZED FRIES REARRANGEMENT OF ARYL ESTERS
OLAH, GA
ARVANAGHI, M
KRISHNAMURTHY, VV
JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (19): : 3359 - 3360
[26] A CONVENIENT METHOD FOR THE FORMATION OF PARA-METHOXYLBENZYL ETHERS AND ESTERS OVER PERFLUORINATED RESINSULFONIC ACID (NAFION-H)
CHO, BR
YANG, HJ
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1992, 13 (06) : 586 - 587
[27] HETEROGENEOUS CATALYSIS BY SOLID SUPERACIDS .12. FRIEDEL-CRAFTS ALKYLATION OF BENZENE, ALKYLBENZENES AND HALOBENZENES WITH ALKYL-HALIDES OVER A PERFLUORINATED RESINSULFONIC ACID (NAFION-H) CATALYST
OLAH, GA
MEIDAR, D
NOUVEAU JOURNAL DE CHIMIE-NEW JOURNAL OF CHEMISTRY, 1979, 3 (04): : 269 - 273
[28] An Environmentally Friendly Nb-P-Si Solid Catalyst for Acid-Demanding Reactions
Aronne, Antonio
Di Serio, Martino
Vitiello, Rosa
Clayden, Nigel J.
Minieri, Luciana
Imparato, Claudio
Piccolo, Alessandro
Pernice, Pasquale
Carniti, Paolo
Gervasini, Antonella
JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (32): : 17378 - 17389
[29] CATALYSIS BY SOLID SUPERACIDS .19. SIMPLIFIED AND IMPROVED POLYMERIC PERFLUORINATED RESIN SULFONIC-ACID (NAFION-H) CATALYZED PROTECTION-DEPROTECTION REACTIONS
OLAH, GA
HUSAIN, A
SINGH, BP
SYNTHESIS-STUTTGART, 1983, (11): : 892 - 895
[30] A Porous Polymer-Based Solid Acid Catalyst with Excellent Amphiphilicity: An Active and Environmentally Friendly Catalyst for the Hydration of Alkynes
Lei, Yizhu
Zhang, Maomin
Li, Qian
Xia, Yu
Leng, Guojun
POLYMERS, 2019, 11 (12)

← 1 2 3 4 5 →