Aroylation of aromatics with arylcarboxylic acids over Nafion-H (polymeric perfluoroalkanesulfonic acid), an environmentally friendly solid acid catalyst

被引：15

作者：

Prakash, GKS ^{[1
]}

Mathew, T

Mandal, M

Farnia, M

Olah, GA

机构：

[1] Univ So Calif, Loker Hydrocarbon Res Inst, Los Angeles, CA 90089 USA

[2] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA

来源：

ARKIVOC | 2004年

关键词：

Nafion-H; Friedel-Crafts aroylation; benzophenones; ionic liquids; trifluoromethylated alcohols;

D O I：

10.3998/ark.5550190.0005.812

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aromatic hydrocarbons undergo direct aroylation with arylcarboxylic acids over Nafion-H, an environmentally friendly, perfluorinated resinsulfonic acid catalyst to give benzophenones and their derivatives. Furthermore, one of the bistrifluoromethylated benzophenone derivative was trifluoromethylated to a new DDT analog.

引用

页码：103 / 110

页数：8

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