Intrinsic hyperpolarizabilities as a figure of merit for electro-optic molecules

被引：47
|
作者：
Zhou, Juefei [1 ]
Kuzyk, Mark G. [1 ]
机构：
[1] Washington State Univ, Dept Phys & Astron, Pullman, WA 99164 USA
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2008年 / 112卷 / 21期
关键词：
D O I：
10.1021/jp7120824
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We propose the scale-invariant intrinsic hyperpolarizability as a measure of the figure of merit for electro-optic molecules. By applying our analysis to the best second-order nonlinear-optical molecules that are made using the present paradigms, we conclude that it should be possible to make dye-doped polymers with electrooptic coefficients of several thousand picometers per volt.
引用
收藏
页码：7978 / 7982
页数：5
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