Intrinsic hyperpolarizabilities as a figure of merit for electro-optic molecules

被引：47

作者：

Zhou, Juefei ^{[1
]}

Kuzyk, Mark G. ^{[1
]}

机构：

[1] Washington State Univ, Dept Phys & Astron, Pullman, WA 99164 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2008年 / 112卷 / 21期

关键词：

D O I：

10.1021/jp7120824

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We propose the scale-invariant intrinsic hyperpolarizability as a measure of the figure of merit for electro-optic molecules. By applying our analysis to the best second-order nonlinear-optical molecules that are made using the present paradigms, we conclude that it should be possible to make dye-doped polymers with electrooptic coefficients of several thousand picometers per volt.

引用

页码：7978 / 7982

页数：5

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