Lutetium(III) oxide bromide, LuOBr

被引:5
|
作者
Zimmermann, Sina [1 ]
Pantenburg, Ingo [1 ]
Meyer, Gerd [1 ]
机构
[1] Univ Cologne, Inst Anorgan Chem, D-50939 Cologne, Germany
关键词
D O I
10.1107/S1600536807027821
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Single crystals of lutetium oxide bromide, LuOBr, were obtained accidentally as a by-product of the reaction of lutetium metal, ruthenium powder and lutetium tribromide, LuBr3, in a sealed tantalum container. As is typical for rare-earth oxide halides of the type REOX (RE = rare-earth metal and X = halogen), LuOBr crystallizes in the tetragonal PbFCl structure type (matlockite), where Lu, O and Br are situated on positions with 4mm, (4) over bar m2 and 4mm symmetry, respectively.
引用
收藏
页码:I156 / U53
页数:9
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