Interaction of thulium, ytterbium(III) and lutetium chlorides with sodium chloride

被引：6

作者：

Büchel, D ^{[1
]}

Seifert, HJ ^{[1
]}

机构：

[1] Univ Gesamthsch Kassel, D-34109 Kassel, Germany

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 1999年 / 57卷 / 01期

关键词：

crystal structures; phase diagrams; ternary lanthanide chlorides; thermodynamic properties;

D O I：

10.1023/A:1010115407242

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The pseudobinary systems NaCl-LnCl(3) (Ln=Tm, Yb, Lu) were investigated by DTA and X-ray diffraction. Two types of ternary chlorides exist: congruently melting compounds Na(3)LnCl(6) with the cryolite-structure, incongruently melting compounds NaLnCl(4) with the NaErCl4-Ln (Ln=Tm) or the NaLnCl(4)-structure (Ln=Yb, Lu). All these structure types contain [LnCl(6)]-octahedra. By solution calorimetry and e.m.f. measurements in galvanic cells for solid electrolytes could be proved that all compounds are formed from NaCl and LnCl(3) by gain in lattice enthalpy.

引用

页码：203 / 208

页数：6

共 50 条

[1] Interaction of Thulium, Ytterbium(III) and Lutetium Chlorides with Sodium Chloride
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