MOCVD of high-k dielectrics, tantalum nitride and copper from directly injected liquid precursors

被引:0
|
作者
Senzaki, Y [1 ]
Hochberg, AK [1 ]
Norman, JAT [1 ]
机构
[1] Schumacher, Carlsbad, CA 92009 USA
来源
关键词
MOCVD; high-k dielectrics; copper CVD; direct liquid injection; tantalum nitride; Ta2O5;
D O I
10.1002/1099-0712(200005/10)10:3/5<93::AID-AMO403>3.3.CO;2-H
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Thin films of tantalum oxide and tantalum nitride for microelectronics applications can be deposited by MOCVD using direct injection of same liquid precursors of the type R-N = Ta(NEt2)(3). High-k mixed-metal oxides, such as Zr-Sn-Ti-O, metal doped TaOx and zirconium silicate, can also be deposited at relatively low temperatures from liquid mixtures as single-source precursors without solvent, This solventless CVD system is considered a more cost effective and environmentally benign process than conventional liquid injection of metal-organic precursors dissolved In organic solvents, In addition, recent advances in copper CVD precursors are reviewed. Copyright (C) 2000 John Wiley & Sons, Ltd.
引用
收藏
页码:93 / 103
页数:11
相关论文
共 50 条
  • [41] Impact of Al-, Ni-, TiN-, and Mo-metal gates on MOCVD-grown HfO2 and ZrO2 high-k dielectrics
    Abermann, S.
    Efavi, J.
    Sjoblom, G.
    Lemme, M.
    Olsson, J.
    Bertagnolli, E.
    MICROELECTRONICS RELIABILITY, 2007, 47 (4-5) : 536 - 539
  • [42] Evolution of the Physics and Stochastics of Failure in Ultra-Thin Dielectrics - From SiO2 to Advanced High-K Gate Stacks
    Raghavan, Nagarajan
    2018 IEEE 8TH INTERNATIONAL NANOELECTRONICS CONFERENCES (INEC), 2018, : 15 - 16
  • [43] Conduction band states of transition metal (TM) high-k gate dielectrics as determined from X-ray absorption spectra
    Lucovsky, G
    Hong, JG
    Fulton, CC
    Stoute, NA
    Zou, Y
    Nemanich, RJ
    Aspnes, DE
    Ade, H
    Schlom, DG
    MICROELECTRONICS RELIABILITY, 2005, 45 (5-6) : 827 - 830
  • [44] Data retention characteristics of nitride-based charge trap memory devices with high-k dielectrics and high-work-function metal gates for multi-gigabit flash memory
    Lee, Jang-Sik
    Kang, Chang-Seok
    Shin, Yoo-Cheol
    Lee, Chanc-Hyun
    Park, Ki-Tae
    Sel, Jong-Sun
    Kim, Viena
    Choe, Byeong-In
    Sim, Jae-Suncy
    Choi, Jungdal
    Kim, Kinam
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2006, 45 (4B): : 3213 - 3216
  • [45] A comparative study of erbium oxide and gadolinium oxide high-k dielectric thin films grown by low-pressure metalorganic chemical vapour deposition (MOCVD) using β-Diketonates as precursors
    Singh, MP
    Thakur, CS
    Shalini, K
    Shripathi, T
    Bhat, N
    Shivashankar, SA
    PHYSICS AND TECHNOLOGY OF HIGH-K GATE DIELECTRICS II, 2004, 2003 (22): : 89 - 99
  • [46] Mobility Enhancement in Solution-Processed Transparent Conductive Oxide TFTs due to Electron Donation from Traps in High-k Gate Dielectrics
    Zeumault, Andre
    Subramanian, Vivek
    ADVANCED FUNCTIONAL MATERIALS, 2016, 26 (06) : 955 - 963
  • [47] Boron nitride nanosheet-induced low dielectric loss and conductivity in PVDF-based high-k ternary composites bearing ionic liquid
    Feng, Yefeng
    Chen, Peiyao
    Zhu, Qiuyin
    Qin, Ben
    Li, Yandong
    Deng, Qihuang
    Li, Xianping
    Li, Xiaoxiao
    Peng, Cheng
    MATERIALS TODAY COMMUNICATIONS, 2021, 26
  • [48] Investigation of Band-Gap Engineered Silicon-Oxide-Nitride-Oxide-Silicon Flash Memory with High-k Dielectrics in Tunnel Barrier and Its Impact on Charge Retention Dynamics
    Jain, Sonal
    Neema, Vaibhav
    Gupta, Deepika
    Vishvakarma, Santosh Kumar
    JOURNAL OF NANOELECTRONICS AND OPTOELECTRONICS, 2016, 11 (06) : 663 - 668
  • [49] Frequency-dependent capacitance reduction in high-k AlTiOx and Al2O3 gate dielectrics from IF to RF frequency range
    Chen, SB
    Lai, CH
    Chan, KT
    Chin, A
    Hsieh, JC
    Liu, J
    IEEE ELECTRON DEVICE LETTERS, 2002, 23 (04) : 203 - 205
  • [50] Review-Investigation and Review of the Thermal, Mechanical, Electrical, Optical, and Structural Properties of Atomic Layer Deposited High-k Dielectrics: Beryllium Oxide, Aluminum Oxide, Hafnium Oxide, and Aluminum Nitride
    Gaskins, John T.
    Hopkins, Patrick E.
    Merrill, Devin R.
    Bauers, Sage R.
    Hadland, Erik
    Johnson, David C.
    Koh, Donghyi
    Yum, Jung Hwan
    Banerjee, Sanjay
    Nordell, Bradley J.
    Paquette, Michelle M.
    Caruso, Anthony N.
    Lanford, William A.
    Henry, Patrick
    Ross, Liza
    Li, Han
    Li, Liyi
    French, Marc
    Rudolph, Antonio M.
    King, Sean W.
    ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, 2017, 6 (10) : N189 - N208