Monodentate, didentate, and tridentate ligation of a Schiff-base ligand in a tetranuclear zinc(II) complex

被引:7
|
作者
Mikuriya, M [1 ]
Ikemi, S [1 ]
Lim, JW [1 ]
机构
[1] Kwansei Gakuin Univ, Sch Sci, Dept Chem, Nishinomiya, Hyogo 6628501, Japan
关键词
D O I
10.1246/bcsj.74.99
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A tetranuclear zinc(II) complex with 2,6-bis(salicylideneaminomethyl)-4-methylphenol (H3L), [Zn-4(L)(2)(pz)(2)]. 2CH(3)CN (Hpz = pyrazole), was synthesized and characterized by H-1 NMR spectroscopy and a single-crystal X-ray diffraction method. Each Schiff-base L3- acts as a monodentate, a didentate, and a tridentate ligand for four zinc atoms to form a Z-shaped tetranuclear structure.
引用
收藏
页码:99 / 100
页数:2
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