New μ-oxo-bridged tetranuclear Cu(II) complex with Schiff-base ligand:: Synthesis, crystal structure and magnetic properties

被引：42
|
作者：
Lu, Han-Wel [1 ]
Huang, Yao-Hsuan [1 ]
Lo, Shun-I [1 ]
Wei, Ho-Hsiang [1 ]
机构：
[1] Tamkang Univ, Dept Chem, Tamsui 25137, Taiwan
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 10期
关键词：
Copper(II) complexes; Copper(II) clusters; crystal structure; magnetic properties;
D O I：
10.1016/j.inoche.2007.07.009
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new mu-oxo-bridged Cu(II) complex with cubane-like tetranuclear copper(II) complex, [Cu-4(L-1)(4)]center dot 4H(2)O (1) (H2L1 = 2-(3-methoxysalicylidene-amino)-benzyl-alcohol), has been prepared, and structurally characterized by X-ray crystallography. Complex 1 crystallized in the monoclinic space group P-21/n and has a tetranuclear core Of Cu4O4. The temperature dependence of magnetic susceptibility measurements shown that complex I exhibits a strong antiferromagnetic interaction with J = 103.4 cm(-1). (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：1210 / 1213
页数：4
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