A New Tetranuclear Cubane-like Ni(II) Complex Based on Schiff-base Ligand: Synthesis, Crystal Structure and Magnetic Properties

被引：10
|
作者：
Lian Qing-Yun [1 ]
Hu Hang-Na [1 ]
Li Can-Hui [1 ]
Li Dong-Ping [1 ]
Jiao Xiao-Yan [1 ]
Li Yong-Xiu [1 ]
机构：
[1] Nanchang Univ, Dept Chem, Nanchang 330031, Jiangxi, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2017年 / 36卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Ni(II) complex; Schiff base; crystal structure; magnetic; CLUSTERS; NICKEL;
D O I：
10.14102/j.cnki.0254-5861.2011-1289
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new Ni(II) cubane-like complex, namely, [Ni(L)(CH3OH)](4)center dot(CH3OH)(2), has been obtained via self-assembly of nickel(II) and Schiff base, where the ligand L is a raceme of (R)-2-[(2-hydroxy-1-phenyl-ethylimino)-methyl]-6-methoxy-phenol. X-ray diffraction analysis reveals that the complex shows a cubane-like [Ni4O4] cluster and similar coordination environment around the metallic centers. Magnetic measurements indicate there is ferromagnetic interaction within the Ni-4 cluster.
引用
收藏
页码：273 / 279
页数：7
相关论文
共 50 条
  • [1] A New Tetranuclear Cubane-like Ni(Ⅱ) Complex Based on Schiff-base Ligand: Synthesis, Crystal Structure and Magnetic Properties
    连庆云
    胡航娜
    李灿辉
    李东平
    焦晓燕
    李永绣
    [J]. Chinese Journal of Structural Chemistry, 2017, 36 (02) : 273 - 279
  • [2] Synthesis, structure, and properties of a tetranuclear cubane-like nickel(II) complex with tridentate Schiff base ligand
    Liu, HY
    Wang, HY
    Niu, DZ
    Lu, ZS
    [J]. SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2005, 35 (10) : 779 - 783
  • [3] New μ-oxo-bridged tetranuclear Cu(II) complex with Schiff-base ligand:: Synthesis, crystal structure and magnetic properties
    Lu, Han-Wel
    Huang, Yao-Hsuan
    Lo, Shun-I
    Wei, Ho-Hsiang
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (10) : 1210 - 1213
  • [4] A New Adamantane-like Tetranuclear Manganese(III) Complex Based on Flexible Schiff-base Ligand: Synthesis, Crystal Structure and Magnetic Property
    Zhang, Ran
    Ni, Zhong-Hai
    Zhang, Li-Fang
    Kou, Hui-Zhong
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2014, 35 (07): : 1965 - 1969
  • [5] A chiral tetranuclear copper(II) complex based on a new Schiff-base ligand: Synthesis, structure, magnetic property and CD spectra
    Xiang, Hua
    Lan, Yanhua
    Jiang, Long
    Zhang, Wei-Xiong
    Anson, Christopher E.
    Lu, Tong-Bu
    Powell, Annie K.
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 16 : 51 - 54
  • [6] Synthesis, structure, and properties of a tetranuclear copper(II) tridentate Schiff-base complex with a pseudo-double-cubane core
    Liu, HY
    Wang, HY
    Wu, H
    Niu, DZ
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2005, 58 (15) : 1345 - 1349
  • [7] Synthesis, Crystal Structure and Magnetic Properties of A Cubane Tetranuclear Copper(II) Complex
    Yan, Xiao Fei
    Pan, Jie
    Li, Shi Rong
    Zhou, Hong
    Pan, Zhi Quan
    [J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2009, 635 (9-10): : 1481 - 1484
  • [8] Synthesis, crystal structure and nonlinear optical properties of nickel(II) complex with Schiff-base ligand
    Xue, ZM
    Zhang, XJ
    Tian, YP
    Wu, JY
    Jiang, MH
    Fun, HK
    [J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 22 (03) : 265 - 269
  • [9] An unexpected cubane-like nickel(II) tetranuclear complex bridged by the anion of 2-hydroxymethylbenzimidazole: Crystal structure and magnetic properties
    Song, Xue-yan
    Xu, Yun-he
    Li, Li-cun
    Liao, Dai-zheng
    Jiang, Zong-hui
    [J]. INORGANICA CHIMICA ACTA, 2007, 360 (06) : 2039 - 2044
  • [10] Synthesis, crystal structure, and magnetic properties of a new tetranuclear Cu(II) Schiff base compound
    Biswas, Moumita
    Pilet, Guillaume
    Tercero, Javier
    El Fallah, M. Salah
    Mitra, Samiran
    [J]. INORGANICA CHIMICA ACTA, 2009, 362 (08) : 2915 - 2920
12345