Synthesis and structure of the highly chlorinated [60]fullerene C60Cl30 with a drum-shaped carbon cage

被引：123
|
作者：
Troshin, PA [1 ]
Lyubovskaya, RN
Ioffe, IN
Shustova, NB
Kemnitz, E
Troyanov, SZ
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Moscow 142432, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
[3] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 02期
关键词：
chlorination; density functional calculations; fullerenes; structure elucidation;
D O I：
10.1002/anie.200461531
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chlorination of C60 with SbCl5, ICl, or ICl 3 at 220-250 °C gives the highly chlorinated fullerene C 60Cl30. The carbon cage of the C60Cl 30 molecule has a unique cylindrical shape (see picture), composed of two aromatic six-membered rings located opposite each other and one equatorial aromatic 18π trannulene belt. DFT calculations suggest that C 60Cl30 is the final product of [60]fullerene chlorination.
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收藏
页码：234 / 237
页数：4
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