Synthesis and structure of the highly chlorinated [60]fullerene C60Cl30 with a drum-shaped carbon cage

被引：123
|
作者：
Troshin, PA [1 ]
Lyubovskaya, RN
Ioffe, IN
Shustova, NB
Kemnitz, E
Troyanov, SZ
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Moscow 142432, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
[3] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 02期
关键词：
chlorination; density functional calculations; fullerenes; structure elucidation;
D O I：
10.1002/anie.200461531
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chlorination of C60 with SbCl5, ICl, or ICl 3 at 220-250 °C gives the highly chlorinated fullerene C 60Cl30. The carbon cage of the C60Cl 30 molecule has a unique cylindrical shape (see picture), composed of two aromatic six-membered rings located opposite each other and one equatorial aromatic 18π trannulene belt. DFT calculations suggest that C 60Cl30 is the final product of [60]fullerene chlorination.
引用
收藏
页码：234 / 237
页数：4
相关论文
共 50 条
  • [21] STRUCTURE AND STABILITY OF STRUCTURE FROM CARBON NANOTUBE AND FULLERENE C-60
    Artyukh, A. A.
    Demin, V. A.
    Chernozatonskiy, L. A.
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 2013, 56 (05): : 88 - +
  • [22] Structure and properties of ionic fullerene complex Co+(dppe)2•(C60•-)•(C6H4Cl2)2: distortion of the ordered fullerene cage of C60•- radical anions
    Konarev, Dmitri V.
    Kuzmin, Alexey V.
    Simonov, Sergey V.
    Khasanov, Salavat S.
    Yudanova, Evgeniya I.
    Lyubovskaya, Rimma N.
    DALTON TRANSACTIONS, 2011, 40 (17) : 4453 - 4458
  • [23] A simple atomic model for hydrogen confined inside a prolate-shaped C60 fullerene cage
    Connerade, JP
    Lyalin, AG
    Semaoune, R
    Semenov, SK
    Solov'yov, AV
    JOURNAL OF PHYSICS B-ATOMIC MOLECULAR AND OPTICAL PHYSICS, 2001, 34 (12) : 2505 - 2511
  • [24] Structure and dynamics of hard carbon formed from C60 fullerene
    Bennington, Stephen M.
    Kitamura, Naoyuki
    Cain, Markys G.
    Lewis, Mike H.
    Arai, Masa
    Physica B: Condensed Matter, 1999, 263 : 632 - 635
  • [25] The structure and dynamics of hard carbon formed from C60 fullerene
    Bennington, SM
    Kitamura, N
    Cain, MG
    Lewis, MH
    Arai, M
    PHYSICA B, 1999, 263 : 632 - 635
  • [26] The reaction of [60]fullerene with atomic carbon synthesis and characterization of C122
    Fabre, TS
    Strongin, RM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U208 - U208
  • [27] Synthesis and structure of fullerene halides in the C60-(TiCl4 + Br2) system: Molecular structures of (C60Cl5)2, C60X6, C60X8, and C60X24(X = Cl, Br)
    S. I. Troyanov
    A. V. Burtsev
    E. Kemnitz
    Crystallography Reports, 2009, 54 : 242 - 249
  • [28] Synthesis and structure of fullerene halides in the C60-(TiCl4 + Br2) system: Molecular structures of (C60Cl5)2, C60 X 6, C60 X 8, and C60 X 24(X = Cl, Br)
    Troyanov, S. I.
    Burtsev, A. V.
    Kemnitz, E.
    CRYSTALLOGRAPHY REPORTS, 2009, 54 (02) : 242 - 249
  • [29] Synthesis of C60(O)3: An Open-Cage Fullerene with a Ketolactone Moiety on the Orifice
    Xin, Nana
    Yang, Xiaobing
    Zhou, Zishuo
    Zhang, Jianxin
    Zhang, Showxin
    Gan, Liangbing
    JOURNAL OF ORGANIC CHEMISTRY, 2013, 78 (03): : 1157 - 1162
  • [30] Synthesis and properties of open-cage fullerene C60 derivatives: impact of the extended π-conjugation
    Hashikawa, Yoshifumi
    Yasui, Hidefumi
    Kurotobi, Kei
    Murata, Yasujiro
    MATERIALS CHEMISTRY FRONTIERS, 2018, 2 (02) : 206 - 213
12345