Synthesis and structure of the highly chlorinated [60]fullerene C60Cl30 with a drum-shaped carbon cage

被引：123
|
作者：
Troshin, PA [1 ]
Lyubovskaya, RN
Ioffe, IN
Shustova, NB
Kemnitz, E
Troyanov, SZ
机构：
[1] Russian Acad Sci, Inst Problems Chem Phys, Moscow 142432, Russia
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
[3] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 02期
关键词：
chlorination; density functional calculations; fullerenes; structure elucidation;
D O I：
10.1002/anie.200461531
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chlorination of C60 with SbCl5, ICl, or ICl 3 at 220-250 °C gives the highly chlorinated fullerene C 60Cl30. The carbon cage of the C60Cl 30 molecule has a unique cylindrical shape (see picture), composed of two aromatic six-membered rings located opposite each other and one equatorial aromatic 18π trannulene belt. DFT calculations suggest that C 60Cl30 is the final product of [60]fullerene chlorination.
引用
收藏
页码：234 / 237
页数：4
相关论文
共 50 条
  • [1] Chemical and electrochemical reduction of the highly chlorinated fullerenes C60Cl24 and C60Cl30
    Troshin, Pavel A.
    Troshina, Olesya A.
    Peregudova, Svetlana M.
    Yudanova, Evgeniya I.
    Buyanovskaya, Anastasiya G.
    Konarev, Dmitry V.
    Peregudov, Alexander S.
    Lapshin, Alexander N.
    Lyubovskaya, Rimma N.
    MENDELEEV COMMUNICATIONS, 2006, 16 (04) : 206 - 208
  • [2] The standard thermodynamic functions of fullerene chloride, C60Cl30
    Druzhinina, A. I.
    Varushchenko, R. M.
    Troyanov, S. I.
    Sidorov, L. N.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2010, 42 (02): : 165 - 168
  • [3] The standard enthalpy of formation of fullerene chloride C60Cl30
    Papina, T. S.
    Luk'yanova, V. A.
    Troyanov, S. I.
    Chelovskaya, N. V.
    Buyanovskaya, A. G.
    Sidorov, L. N.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 81 (02) : 159 - 163
  • [4] The standard enthalpy of formation of fullerene chloride C60Cl30
    T. S. Papina
    V. A. Luk’yanova
    S. I. Troyanov
    N. V. Chelovskaya
    A. G. Buyanovskaya
    L. N. Sidorov
    Russian Journal of Physical Chemistry A, 2007, 81 : 159 - 163
  • [5] Electronic Structure of the Chlorinated Fullerene C60Cl30 Studied by Quantum Chemical Modeling of X-Ray Absorption Spectra
    Fedoseeva, Yu. V.
    Bulusheva, L. G.
    Okotrub, A. V.
    Asanov, I. P.
    Troyanov, S. I.
    Vyalikh, D. V.
    INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2011, 111 (11) : 2688 - 2695
  • [6] Valence band of the chlorinated fullerene C60Cl30 probed by photoemission and X-ray emission spectroscopy
    Lavskaya, Yu. V.
    Duda, T. A.
    Troyanov, S. I.
    Asanov, I. P.
    Bulusheva, L. G.
    Okotrub, A. V.
    JOURNAL OF MOLECULAR STRUCTURE, 2009, 921 (1-3) : 264 - 267
  • [7] Preparation and spectroscopic properties of chlorofullerenes C60Cl24, C60Cl28, and C60Cl30
    Troshin, Pavel A.
    Lapinski, Andrzej
    Bogucki, Andrzej
    Polomska, Maria
    Lyubovskaya, Rimma N.
    CARBON, 2006, 44 (13) : 2770 - 2777
  • [8] A Quantum Chemical Study of C60Cl30, C60(OH)30 Molecules and Fe@C60(OH)30 Endocomplex
    Semenov, S. G.
    Bedrina, M. E.
    Titov, A. V.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 59 (03) : 506 - 511
  • [9] A Quantum Chemical Study of C60Cl30, C60(OH)30 Molecules and Fe@C60(OH)30 Endocomplex
    S. G. Semenov
    M. E. Bedrina
    A. V. Titov
    Journal of Structural Chemistry, 2018, 59 : 506 - 511
  • [10] Preparation and structural characterization of two kinetically stable chlorofullerenes, C60Cl28 and C60Cl30
    Troyanov, SI
    Shustova, NB
    Popov, AA
    Sidorov, LN
    Kemnitz, E
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (03) : 432 - 435
12345