Mirror symmetry breaking upon spontaneous crystallization from a dynamic combinatorial library of macrocyclic imines

被引：16
|
作者：
Ziach, Krzysztof [1 ]
Jurczak, Janusz [2 ]
机构：
[1] Univ Warsaw, Fac Chem, PL-02093 Warsaw, Poland
[2] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 20期
关键词：
ACHIRAL MOLECULES; STATE; AMPLIFICATION; GENERATION;
D O I：
10.1039/c4cc10083b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Spontaneous emergence of solid state chirality and mirror symmetry breaking occurred upon crystallization from a small templated dynamic combinatorial library (DCL) of achiral macrocyclic imines, and depended strongly on the nature of library building blocks (amines, aldehydes, template cations and anions) and crystallization temperature.
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页码：4306 / 4309
页数：4
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