Mirror symmetry breaking upon spontaneous crystallization from a dynamic combinatorial library of macrocyclic imines

被引：16
|
作者：
Ziach, Krzysztof [1 ]
Jurczak, Janusz [2 ]
机构：
[1] Univ Warsaw, Fac Chem, PL-02093 Warsaw, Poland
[2] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 20期
关键词：
ACHIRAL MOLECULES; STATE; AMPLIFICATION; GENERATION;
D O I：
10.1039/c4cc10083b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Spontaneous emergence of solid state chirality and mirror symmetry breaking occurred upon crystallization from a small templated dynamic combinatorial library (DCL) of achiral macrocyclic imines, and depended strongly on the nature of library building blocks (amines, aldehydes, template cations and anions) and crystallization temperature.
引用
收藏
页码：4306 / 4309
页数：4
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