Copper-free click chemistry for the in situ crosslinking of photodegradable star polymers

被引：156
|
作者：
Johnson, Jeremiah A. [1 ]
Baskin, Jeremy M. [2 ,3 ,4 ]
Bertozzi, Carolyn R. [2 ,3 ,4 ,5 ]
Koberstein, Jeffrey T. [6 ]
Turro, Nicholas J. [1 ,6 ]
机构：
[1] Columbia Univ, Dept Chem, New York, NY 10027 USA
[2] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Dept Mol & Cell Biol, Berkeley, CA 94720 USA
[4] Univ Calif Berkeley, Howard Hughes Med Inst, Berkeley, CA 94720 USA
[5] Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA
[6] Columbia Univ, Dept Chem Engn, New York, NY 10027 USA
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 26期
基金：
美国国家科学基金会;
关键词：
D O I：
10.1039/b803043j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Bifunctional,fluorinated cyclooctynes were used for the in situ "click'' crosslinking of azide-terminated photodegradable star polymers, yielding photodegradable polymeric model networks with well-defined structures and tunable gelation times.
引用
收藏
页码：3064 / 3066
页数：3
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