One-pot synthesis of small spirocarbocycles through the catalytic cyclometalation reactions of unsaturated compounds

被引：14

作者：

D'yakonov, Vladimir A. ^{[1
]}

Tuktarova, Regina A. ^{[1
]}

Trapeznikova, Olga A. ^{[1
]}

Khalilov, Leonard M. ^{[1
]}

Popod'ko, Natal'ya R. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochem & Catalysis, 141 Prospekt Oktyabrya, Ufa 450075, Russia

来源：

ARKIVOC | 2011年

基金：

俄罗斯基础研究基金会;

关键词：

Cyclometallation; cyclopropanation; homogeneous catalysis; spiranes; cyclopropane; cyclobutane; Dzhemilev reaction; TRANSFORMATIONS; CYCLOMAGNESIATION; CHEMISTRY; CYCLONONA-1,2-DIENE; CYCLOALUMINATION; CARBOALUMINATION; ORGANOALUMINUM; METALLACYCLES; CONVERSION; OLEFINS;

D O I：

10.3998/ark.5550190.0012.802

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The mild and efficient one-pot methods to synthesize substituted spirocyclopropanes and spirocyclobutanes are reported. The elaborated procedures based on consecutive cycloalumination of methylenecyclopropanes, methylenecyclobutanes or cycloalkynes assisted by alkyl aluminums and Cp2ZrCl2 as a catalyst provide the formation of target products through Pd catalyzed carbocyclization of the aluminacyclopentane and aluminacyclopentene intermediates with Me2SO4 or allyl chloride.

引用

页码：20 / 33

页数：14

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