One-pot synthesis of small spirocarbocycles through the catalytic cyclometalation reactions of unsaturated compounds

被引：14

作者：

D'yakonov, Vladimir A. ^{[1
]}

Tuktarova, Regina A. ^{[1
]}

Trapeznikova, Olga A. ^{[1
]}

Khalilov, Leonard M. ^{[1
]}

Popod'ko, Natal'ya R. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochem & Catalysis, 141 Prospekt Oktyabrya, Ufa 450075, Russia

来源：

ARKIVOC | 2011年

基金：

俄罗斯基础研究基金会;

关键词：

Cyclometallation; cyclopropanation; homogeneous catalysis; spiranes; cyclopropane; cyclobutane; Dzhemilev reaction; TRANSFORMATIONS; CYCLOMAGNESIATION; CHEMISTRY; CYCLONONA-1,2-DIENE; CYCLOALUMINATION; CARBOALUMINATION; ORGANOALUMINUM; METALLACYCLES; CONVERSION; OLEFINS;

D O I：

10.3998/ark.5550190.0012.802

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The mild and efficient one-pot methods to synthesize substituted spirocyclopropanes and spirocyclobutanes are reported. The elaborated procedures based on consecutive cycloalumination of methylenecyclopropanes, methylenecyclobutanes or cycloalkynes assisted by alkyl aluminums and Cp2ZrCl2 as a catalyst provide the formation of target products through Pd catalyzed carbocyclization of the aluminacyclopentane and aluminacyclopentene intermediates with Me2SO4 or allyl chloride.

引用

页码：20 / 33

页数：14

共 50 条

[31] One-pot dehydrogenation of carboxylic acid derivatives to α,β-unsaturated carbonyl compounds
Matsuo, J
LETTERS IN ORGANIC CHEMISTRY, 2005, 2 (07) : 576 - 577
[32] Synthesis of polycyclic indolizine derivatives via one-pot tandem reactions of N-ylides with dichloro substituted α,β-unsaturated carbonyl compounds
Liu, Yun
Hu, Hua-You
Liu, Qing-Jian
Hu, Hong-Wen
Xu, Jian-Hua
TETRAHEDRON, 2007, 63 (09) : 2024 - 2033
[33] SYNTHESIS THROUGH REACTIONS OF NUCLEOPHILES WITH ACRYLONITRILES .13. A DIRECT ONE-POT SYNTHESIS OF THIAZOLOPYRIDINES
ABDELLATIF, FF
MOHAMMED, YS
ABDELGHANI, H
AHMED, EK
ELGAWISH, EH
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1993, 78 (1-4): : 251 - 256
[34] Chemists clean up synthesis with one-pot reactions
Science, 1994, 266 (5182)
[35] One-pot synthesis of imaging agents by multicomponent reactions
Jauregui, Maite
Faulkner, Stephen
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233 : 694 - 694
[36] Catalytic One-Pot Production of Small Organics from Polysaccharides
Verendel, J. Johan
Church, Tamara L.
Andersson, Pher G.
SYNTHESIS-STUTTGART, 2011, (11): : 1649 - 1677
[37] One-Pot Synthesis of Novel Photochromic Oxazine Compounds
Zhao, Weili
Carreira, Erick M.
ORGANIC LETTERS, 2011, 13 (19) : 5084 - 5087
[38] Study on catalytic synthesis of methanol from syngas via methylformate in heterogeneous ''one-pot'' reactions
Zhang, HB
Li, HY
Lin, GD
Liu, Y
Tsai, KR
11TH INTERNATIONAL CONGRESS ON CATALYSIS - 40TH ANNIVERSARY, PTS A AND B, 1996, 101 : 1369 - 1378
[39] Convenient one-pot synthesis of β-alkyl thio acid derivatives from thioacetates and the corresponding α,β-unsaturated compounds
Department of Chemistry, Sogang University, Seoul 121-742, Korea, Republic of
Synth. Commun., 11 (2189-2196):
[40] Cross Metathesis of N-Allylamines and α,β-Unsaturated Carbonyl Compounds: A One-Pot Synthesis of Substituted Pyrroles
Shafi, Syed
Kedziorek, Mariusz
Grela, Karol
SYNLETT, 2011, (01) : 124 - 128

← 1 2 3 4 5 →