Activation of Mesitylene Involving Multiple Carbon-Carbon Bond Formation under Ambient Conditions with Regeneration of the Organoiron Precursor

被引：5
|
作者：
Sander, Anett C. [1 ]
Ruiz, Jaime [1 ]
Astruc, Didier [1 ]
机构：
[1] Univ Bordeaux 1, Inst Mol Sci, UMR CNRS 5255, F-33405 Talence, France
来源：
ORGANOMETALLICS | 2010年 / 29卷 / 21期
关键词：
ELECTRON RESERVOIR COMPLEXES; ACETONITRILE; FERROCENE; ROUTE; SANDWICHES;
D O I：
10.1021/om100168x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The CpFe+-induced nona-allylation of mesitylene was largely improved by scaling up and carrying out the reaction of [FeCp(eta(6)-1,3.5-C6H3Me3][PF6] with KOH/DME under ambient conditions (95% yield), followed by recycling this organoiron precursor by visible-light photolysis in CH2Cl2 using a 100 W desk lamp in the presence of mesitylene (95% recovery yield).
引用
收藏
页码：5722 / 5724
页数：3
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