Activation of Mesitylene Involving Multiple Carbon-Carbon Bond Formation under Ambient Conditions with Regeneration of the Organoiron Precursor

被引：5
|
作者：
Sander, Anett C. [1 ]
Ruiz, Jaime [1 ]
Astruc, Didier [1 ]
机构：
[1] Univ Bordeaux 1, Inst Mol Sci, UMR CNRS 5255, F-33405 Talence, France
来源：
ORGANOMETALLICS | 2010年 / 29卷 / 21期
关键词：
ELECTRON RESERVOIR COMPLEXES; ACETONITRILE; FERROCENE; ROUTE; SANDWICHES;
D O I：
10.1021/om100168x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The CpFe+-induced nona-allylation of mesitylene was largely improved by scaling up and carrying out the reaction of [FeCp(eta(6)-1,3.5-C6H3Me3][PF6] with KOH/DME under ambient conditions (95% yield), followed by recycling this organoiron precursor by visible-light photolysis in CH2Cl2 using a 100 W desk lamp in the presence of mesitylene (95% recovery yield).
引用
收藏
页码：5722 / 5724
页数：3
相关论文
共 50 条
  • [21] Mechanistic insight into carbon-carbon bond formation on cobalt under simulated Fischer-Tropsch synthesis conditions
    C. J. (Kees-Jan) Weststrate
    Devyani Sharma
    Daniel Garcia Rodriguez
    Michael A. Gleeson
    Hans O. A. Fredriksson
    J. W. (Hans) Niemantsverdriet
    Nature Communications, 11
  • [22] Carbon-Carbon Bond Formation Involving a Vinylidene Ligand and Ferrocenyl Substituent in Cationic Ruthenium Complexes
    Chang, Li-Han
    Yeh, Cheng-Wei
    Ma, Hao-Wei
    Liu, Shu-Yu
    Lin, Ying-Chih
    Wang, Yu
    Liu, Yi-Hong
    ORGANOMETALLICS, 2010, 29 (05) : 1092 - 1099
  • [23] Carbon-carbon bond formation via directed C-H activation.
    Sezen, B
    Franz, R
    Sames, D
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : A23 - A23
  • [24] Recent Advances in Light-Driven Carbon-Carbon Bond Formation via Carbon Dioxide Activation
    Jung, Jieun
    Saito, Susumu
    SYNTHESIS-STUTTGART, 2021, 53 (18): : 3263 - 3278
  • [25] Carbon-carbon and Carbon-heteroatom Bond Forming Reactions Under Greener Conditions - Part 2
    Banerjee, Bubun
    CURRENT ORGANIC CHEMISTRY, 2021, 25 (01) : 2 - 3
  • [26] Investigations directed at catalytic carbon-carbon and carbon-oxygen bond formation via C-H bond activation
    Blackmore, Ian J.
    Semiao, Christopher J.
    Buschhaus, Miriam S. A.
    Patrick, Brian O.
    Legzdins, Peter
    ORGANOMETALLICS, 2007, 26 (20) : 4881 - 4889
  • [27] HETEROBIMETALLIC TEMPLATES FOR CARBON-CARBON BOND FORMATION BY MIGRATORY INSERTION REACTIONS INVOLVING CO, ISONITRILES OR OLEFINS
    BRAUNSTEIN, P
    KNORR, M
    STAHRFELDT, T
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (17) : 1913 - 1914
  • [28] Intramolecular electron transfer initiated cation and radical formation through carbon-carbon bond activation
    Tu, Wangyang
    Floreancig, Paul E.
    ORGANIC LETTERS, 2007, 9 (12) : 2389 - 2392
  • [29] Mechanistic investigation of catalytic carbon-carbon bond activation and formation by platinum and palladium phosphine complexes
    Edelbach, BL
    Lachicotte, RJ
    Jones, WD
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (12) : 2843 - 2853
  • [30] Monowave microwave activation: green formation of carbon-carbon bond in solvent free Tiedtke reaction
    Villemin, Didier
    Dridi, Feryel
    Bar, Nathalie
    Benmeddah, Amel
    ARKIVOC, 2022, : 10 - 22
12345