Synthesis of a cycloallin derivative from β-cyclodextrin:: Heptakis(2,3-dideoxy-2,3-epithio)-β-cycloallin

被引：6

作者：

Fukudome, M

Shiratani, T

Immel, S

Nogami, Y

Yuan, DQ

Fujita, K ^{[1
]}

机构：

[1] Nagasaki Univ, Grad Sch Biomed Sci, Dept Mol Med Sci, Nagasaki 8528521, Japan

[2] Daiichi Coll Pharmaceut Sci, Fukuoka 8128511, Japan

[3] Tech Univ Darmstadt, Clemems Schopf Inst Organ Chem & Biochem, D-64287 Darmstadt, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 27期

关键词：

cyclic oligosaccharides; cycloallin; cyclodextrins; episulfides;

D O I：

10.1002/anie.200462678

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Made from sugar: Heptakis (2,3-dideoxy-2,3-epithio)- β-cycloallin has been synthesized in a one-pot procedure from a β-cyclodextrin derivative. Molecular modeling studies suggest that the structure of the cycloallin is inverted relative to that of regular cyclodextrins, with the sulfur atoms of the epithio groups pointing inwards to form the narrower aperture (see model; S yellow, O red, C gray, H white). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4201 / 4204

页数：4

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