Synthesis and Molecular Structure of trans-[IrCl(NO)(PtBu2H)2]BF4

被引：3
|
作者：
Boettcher, Hans-Christian [1 ]
Mies, Thomas [1 ]
Mayer, Peter [1 ]
机构：
[1] Univ Munich, Dept Chem, Butenandtstr 5-13 D, D-81377 Munich, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2016年 / 642卷 / 14期
关键词：
Nitrosyl complexes; Iridium; Secondary phosphanes; Crystal structure; CONFORMATIONAL EXCHANGE ITINERARIES; STEREODYNAMICS; COMPLEXES; LIGANDS; RH(I); IR(I);
D O I：
10.1002/zaac.201600182
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis and structural characterization of trans-[IrCl(NO)(PtBu2H)(2)]BF4 (1) is reported. The title compound was prepared in good yield in the reaction of in situ-prepared trans-[IrCl(coe)(PtBu2H)(2)] (coe = cis-cyclooctene) with an appropriate amount of nitrosonium tetrafluoridoborate in dichloromethane at room temperature. Single crystals of 1 were grown from dichloromethane/diethyl ether and were analyzed by X-ray crystallography.
引用
收藏
页码：793 / 795
页数：3
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