Crystal and molecular structure of trans-[RhCl(CO)(PtBu2Ph)2]

被引：1

作者：

Mayer, Peter ^{[1
]}

Boettcher, Hans-Christian ^{[1
]}

机构：

[1] Ludwig Maximilians Univ Munchen, Dept Chem, Butenandtstr 5-13, D-81377 Munich, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2018年 / 73卷 / 12期

关键词：

crystal structure; metal carbonyls; phosphane complex; rhodium(I); STEREODYNAMICS; RHODIUM; NMR;

D O I：

10.1515/znb-2018-0163

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of THF solutions containing the rhodium(II) complex trans-[RhCl2(Mu(2)Ph)(2)] (1) with [Fe-2(Co)(9)] in the same solvent resulted in the formation of the Vaska-type complex trans-[RhCl(CO)((PBu2Ph)-Bu-t)(2)] (2) in high yield. The title complex 2 was obtained as pale yellow crystals, characterized by NMR and IR spectroscopy, as well as by microanalyses. Additionally, the molecular structure of 2 has been established by X-ray crystallography. As often reported for similar constituted compounds, the chlorido and carbonyl ligands in crystals of 2 are strongly disordered.

引用

页码：1029 / 1032

页数：4

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