Crystal and molecular structure of trans-[RhCl(CO)(PtBu2Ph)2]

被引：1

作者：

Mayer, Peter ^{[1
]}

Boettcher, Hans-Christian ^{[1
]}

机构：

[1] Ludwig Maximilians Univ Munchen, Dept Chem, Butenandtstr 5-13, D-81377 Munich, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2018年 / 73卷 / 12期

关键词：

crystal structure; metal carbonyls; phosphane complex; rhodium(I); STEREODYNAMICS; RHODIUM; NMR;

D O I：

10.1515/znb-2018-0163

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of THF solutions containing the rhodium(II) complex trans-[RhCl2(Mu(2)Ph)(2)] (1) with [Fe-2(Co)(9)] in the same solvent resulted in the formation of the Vaska-type complex trans-[RhCl(CO)((PBu2Ph)-Bu-t)(2)] (2) in high yield. The title complex 2 was obtained as pale yellow crystals, characterized by NMR and IR spectroscopy, as well as by microanalyses. Additionally, the molecular structure of 2 has been established by X-ray crystallography. As often reported for similar constituted compounds, the chlorido and carbonyl ligands in crystals of 2 are strongly disordered.

引用

页码：1029 / 1032

页数：4

共 50 条

[41] First catalytic dihydroamination of a phosphaalkyne. Crystal and molecular structure of trans-[PdCl2{P(PriNH)2CH2But}2]
Cloke, FGN
Hitchcock, PB
Nixon, JF
Wilson, DJ
[J]. CHEMICAL COMMUNICATIONS, 2000, (23) : 2387 - 2388
[42] Bridge-splitting of trans-[PtCl2(η2-CH2=CH2)]2 by weak nucleophiles: Crystal and molecular structure of trans-[PtCl2(η2-CH2=CH2)(MeCN)]
Otto, Stefanus
Roodt, Andreas
Elding, Lars I.
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2009, 12 (08) : 766 - 768
[43] Carbonylation reaction of alkyl complexes of iron and molecular structure of cis,trans-[Fe(CO)(2)(PME3)(2)(CH3)I] and trans,trans-[Fe(CO)(2)(PMe3)(2)(CH3)I]
Bellachioma, G
Cardaci, G
Macchioni, A
Reichenbach, G
Foresti, E
Sabatino, P
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 531 (1-2) : 227 - 235
[44] POLARIZED CRYSTAL SPECTRA OF OPTICALLY ACTIVE IONS .I. TRANS-[CO(1-PN)2CL2]+ AND TRANS-[COEN2CL2]+
DINGLE, R
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 46 (01): : 1 - &
[45] Preparation and crystal structure of trans-(Ph(4)As)(2)[OsCl2(NCS)(2)(c)(SCN)(2)(c)], vibrational spectra and normal coordinate analysis
Semrau, M
Preetz, W
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (09): : 1537 - 1541
[46] PREPARATION AND MOLECULAR AND CRYSTAL-STRUCTURE OF TRANS-(R,S)-[CR(2,3,2-TET)(NCS)2]NCS
MACKE, HR
MENTZEN, BF
PUAUX, JP
ADAMSON, AW
[J]. INORGANIC CHEMISTRY, 1982, 21 (08) : 3080 - 3082
[47] REACTIONS OF THE COMPLEXES PT3(MU-CO)3L3 WITH SO2 - CRYSTAL-STRUCTURE OF PT3(MU-CO)3(PTBU2PH)3.0.25(C4H8O)
BURROW, RA
FARRAR, DH
IRWIN, JJ
[J]. INORGANICA CHIMICA ACTA, 1991, 181 (01) : 65 - 72
[48] CRYSTAL STRUCTURE OF [RH(F6FOS)2]+[CIS-(CO)2RHCL2]-
EINSTEIN, FW
HAMPTON, CRS
[J]. CANADIAN JOURNAL OF CHEMISTRY, 1971, 49 (11): : 1901 - &
[49] CRYSTAL STRUCTURE OF RhCl（dppm）2·H2O
Shao Chang-Ping Cheng Guo-Bao Wang Je-Yu Guo He-FuDalian Institute of Chemical Physics
[J]. Chinese Journal of Structural Chemistry, 1993, (05) : 343 - 345
[50] SYNTHESIS AND CHARACTERIZATION OF BIFUNCTIONAL TRANS-(PH(3)P)(2)PT(CO(2)ME)(X) COMPLEXES
MERWIN, RK
RODDICK, DM
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 487 (1-2) : 69 - 75

← 1 2 3 4 5 →