Synthesis and Molecular Structure of trans-[IrCl(NO)(PtBu2H)2]BF4

被引：3

作者：

Boettcher, Hans-Christian ^{[1
]}

Mies, Thomas ^{[1
]}

Mayer, Peter ^{[1
]}

机构：

[1] Univ Munich, Dept Chem, Butenandtstr 5-13 D, D-81377 Munich, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2016年 / 642卷 / 14期

关键词：

Nitrosyl complexes; Iridium; Secondary phosphanes; Crystal structure; CONFORMATIONAL EXCHANGE ITINERARIES; STEREODYNAMICS; COMPLEXES; LIGANDS; RH(I); IR(I);

D O I：

10.1002/zaac.201600182

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structural characterization of trans-[IrCl(NO)(PtBu2H)(2)]BF4 (1) is reported. The title compound was prepared in good yield in the reaction of in situ-prepared trans-[IrCl(coe)(PtBu2H)(2)] (coe = cis-cyclooctene) with an appropriate amount of nitrosonium tetrafluoridoborate in dichloromethane at room temperature. Single crystals of 1 were grown from dichloromethane/diethyl ether and were analyzed by X-ray crystallography.

引用

页码：793 / 795

页数：3

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