Three-dimensional network with cavities created by hydrogen bonds in protocatechuic acid/copper(II) system

被引：1
|
作者：
Zhu, LG [1 ]
Kitagawa, S [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
来源：
FRONTIERS OF SOLID STATE CHEMISTRY | 2002年
关键词：
D O I：
10.1142/9789812776846_0048
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new complex, (Cu-2(phen)(6)(H(3)PCA)(4)(NO3)(4)-2H(2)O) (1), was synthesized and structurally characterized. Crystal data for the complex I are as follows: Cu2C100N16O30H76, FW=2108.88, monoclinic, space group Cc, a=1.0039(1) nm, b=3.9152(5) nm, c=2.41074(7) nm, beta=102.0370(7)degrees, V=9.267(1) nm(3), Z=4, R-1=0.053 and R-W=0.058. The complex is composed of copper cations, nitrate anions, 1,10-phenanthroline, protocatechuic acid and lattice water molecules. The structure of H(3)PCA, NO3- and waters comprises packing of three-dimensional network by hydrogen bonds with cavities. The complex can be considered as a model of host/guest supermolecule. The three-dimensional hydrogen-bonding network is the host species. The Cu(phen)(3)(2+) cations, guest species, occupy the cavities of the host.
引用
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页码：355 / 360
页数：6
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