The first electrochemical and surface analysis of 2-aminobenzimidazole as a corrosion inhibitor for copper in chloride solution

被引:28
|
作者
Xhanari, Klodian [1 ,2 ]
Finsgar, Matjaz [1 ]
机构
[1] Univ Maribor, Fac Chem & Chem Engn, Smetanova Ul 17, SLO-2000 Maribor, Slovenia
[2] Univ Tirana, Fac Nat Sci, Blvd Zogu I, Tirana 1001, Albania
关键词
RAY PHOTOELECTRON-SPECTROSCOPY; CYCLIC NITROGEN-COMPOUNDS; LONG-TERM IMMERSION; NACL SOLUTION; MEDIA; AZOLES; STEEL; XPS; 1,2,3-BENZOTRIAZOLE; BENZOTRIAZOLE;
D O I
10.1039/c7nj01209h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
For the first time, 2-aminobenzimidazole (2-ABI) was tested as a corrosion inhibitor for copper in 3 wt% NaCl solution at 25 degrees C using cyclic voltammetry (CV), chronopotentiometry, electrochemical impedance spectroscopy (EIS), and potentiodynamic curve (PD) techniques. The EIS measurements indicated that the corrosion of Cu in the presence of 2-ABI followed kinetic- and diffusion-controlled processes. After 100 h of immersion, the potentiodynamic curves showed that 2-ABI acts as a mixed-type inhibitor, with a predominant action on the anodic corrosion reaction. ATR-FTIR confirmed the adsorption of 2-ABI on the Cu surface, which resulted in increased hydrophobicity of the copper surface and reduced its surface roughness.
引用
收藏
页码:7151 / 7161
页数:11
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