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The first electrochemical and surface analysis of 2-aminobenzimidazole as a corrosion inhibitor for copper in chloride solution
被引:28
|作者:
Xhanari, Klodian
[1
,2
]
Finsgar, Matjaz
[1
]
机构:
[1] Univ Maribor, Fac Chem & Chem Engn, Smetanova Ul 17, SLO-2000 Maribor, Slovenia
[2] Univ Tirana, Fac Nat Sci, Blvd Zogu I, Tirana 1001, Albania
关键词:
RAY PHOTOELECTRON-SPECTROSCOPY;
CYCLIC NITROGEN-COMPOUNDS;
LONG-TERM IMMERSION;
NACL SOLUTION;
MEDIA;
AZOLES;
STEEL;
XPS;
1,2,3-BENZOTRIAZOLE;
BENZOTRIAZOLE;
D O I:
10.1039/c7nj01209h
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
For the first time, 2-aminobenzimidazole (2-ABI) was tested as a corrosion inhibitor for copper in 3 wt% NaCl solution at 25 degrees C using cyclic voltammetry (CV), chronopotentiometry, electrochemical impedance spectroscopy (EIS), and potentiodynamic curve (PD) techniques. The EIS measurements indicated that the corrosion of Cu in the presence of 2-ABI followed kinetic- and diffusion-controlled processes. After 100 h of immersion, the potentiodynamic curves showed that 2-ABI acts as a mixed-type inhibitor, with a predominant action on the anodic corrosion reaction. ATR-FTIR confirmed the adsorption of 2-ABI on the Cu surface, which resulted in increased hydrophobicity of the copper surface and reduced its surface roughness.
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页码:7151 / 7161
页数:11
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