Copper-catalyzed direct decarboxylative fluorosulfonylation of aliphatic carboxylic acids

被引：29

作者：

Yi, Ji-Tao ^{[1
]}

Zhou, Xiang ^{[1
]}

Chen, Qi-Long ^{[1
]}

Chen, Zhi-Da ^{[1
]}

Lu, Gui ^{[1
]}

Weng, Jiang ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Pharmaceut Sci, Guangdong Prov Key Lab Chiral Mol & Drug Discover, Guangzhou 510006, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2022年 / 58卷 / 67期

关键词：

C-H BONDS; SULFONYL FLUORIDES; SULFUR-DIOXIDE; SUFEX; FUNCTIONALIZATION;

D O I：

10.1039/d2cc03221j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sulfonyl fluorides are emerging as key structural motifs in organic synthesis, medicinal chemistry, and materials science. Herein we report two efficient and complementary methods for direct decarboxylative fluorosulfonylation of carboxylic acids by the merging of copper catalysis with different N-centered HAT regents. A wide range of structurally diverse sulfonyl fluorides was readily accessed from primary, secondary, and tertiary carboxylic acids in a single step under mild conditions.

引用

页码：9409 / 9412

页数：4

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