Aliphatic sulfonyl fluoride synthesis via reductive decarboxylative fluorosulfonylation of aliphatic carboxylic acid NHPI esters

被引：42
|
作者：
Ma, Zhanhu [1 ]
Liu, Yongan [2 ]
Ma, Xiaoyu [1 ]
Hu, Xiaojun [1 ]
Guo, Yong [2 ]
Chen, Qing-Yun [2 ]
Liu, Chao [1 ,2 ]
机构：
[1] Shanghai Inst Technol, Sch Chem & Environm Engn, 100 Haiquan Rd, Shanghai 201418, Peoples R China
[2] Chinese Acad Sci, Univ Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2022年 / 9卷 / 04期
基金：
中国国家自然科学基金;
关键词：
SUFEX CLICK CHEMISTRY; ONE-POT; REAGENT;
D O I：
10.1039/d1qo01655e
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Based on a radical sulfur dioxide insertion and fluorination strategy, we have developed an efficient method for aliphatic sulfonyl fluoride synthesis using abundant carboxylic acids, a reductant, a sulfur dioxide surrogate and the electrophilic fluorination reagent N-fluorobenzenesulfonimide (NFSI) under reduction conditions. This protocol provides a convenient synthetic pathway for various aliphatic sulfonyl fluorides and tolerates a wide range of functional groups.
引用
收藏
页码：1115 / 1120
页数：6
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