Aliphatic sulfonyl fluoride synthesis via reductive decarboxylative fluorosulfonylation of aliphatic carboxylic acid NHPI esters

被引：42

作者：

Ma, Zhanhu ^{[1
]}

Liu, Yongan ^{[2
]}

Ma, Xiaoyu ^{[1
]}

Hu, Xiaojun ^{[1
]}

Guo, Yong ^{[2
]}

Chen, Qing-Yun ^{[2
]}

Liu, Chao ^{[1
,2
]}

机构：

[1] Shanghai Inst Technol, Sch Chem & Environm Engn, 100 Haiquan Rd, Shanghai 201418, Peoples R China

[2] Chinese Acad Sci, Univ Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China

来源：

ORGANIC CHEMISTRY FRONTIERS | 2022年 / 9卷 / 04期

基金：

中国国家自然科学基金;

关键词：

SUFEX CLICK CHEMISTRY; ONE-POT; REAGENT;

D O I：

10.1039/d1qo01655e

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Based on a radical sulfur dioxide insertion and fluorination strategy, we have developed an efficient method for aliphatic sulfonyl fluoride synthesis using abundant carboxylic acids, a reductant, a sulfur dioxide surrogate and the electrophilic fluorination reagent N-fluorobenzenesulfonimide (NFSI) under reduction conditions. This protocol provides a convenient synthetic pathway for various aliphatic sulfonyl fluorides and tolerates a wide range of functional groups.

引用

页码：1115 / 1120

页数：6

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