Temperature-Induced Structural Phase Transitions in Self-Assembled Hydrogen Bonded Networks at the Liquid/Solid Interface

被引：4
|
作者：
Qiu, Shenyu [1 ]
Li, Yudie [1 ]
Xu, Shilin [1 ]
Cai, Yuanqing [1 ]
Zhang, Yuxin [1 ]
Li, Wei [1 ]
机构：
[1] Nanchang Inst Technol, Dept Sci, Nanchang 330099, Jiangxi, Peoples R China
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2021年 / 95卷 / 09期
基金：
中国国家自然科学基金;
关键词：
self-assembly; temperature regulation; structural transition; scanning tunneling microscopy; TOTAL-ENERGY CALCULATIONS; TRIMESIC ACID; SOLID INTERFACE; 2D; CU(111);
D O I：
10.1134/S0036024421090247
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The effect of temperature on the transformations of hydrogen-bonded structures of trimesic acid (TMA) and p-terphenyl-3,5,3'',5''-tetracarboxylic acid (TPTC) has been investigated at the nonanoic acid/highly oriented pyrolytic graphite (HOPG) interface by scanning tunneling microscopy (STM). STM observations show that TMA assembly based on temperature modulations underwent phase transitions from a chicken-wire (25 degrees C) to a flower (60 degrees C) and further to a guest-host flower structure. Similarly, TPTC network with five kinds of pores underwent change of structural conformation after annealing to 85 degrees C. This work provides a way toward controlled assembly directed by temperature and is beneficial for the understanding of both the assembling process and the underlying kinetics and thermodynamics for molecular nanostructures.
引用
收藏
页码：1871 / 1876
页数：6
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