Temperature-Induced Structural Phase Transitions in Self-Assembled Hydrogen Bonded Networks at the Liquid/Solid Interface

被引：4

作者：

Qiu, Shenyu ^{[1
]}

Li, Yudie ^{[1
]}

Xu, Shilin ^{[1
]}

Cai, Yuanqing ^{[1
]}

Zhang, Yuxin ^{[1
]}

Li, Wei ^{[1
]}

机构：

[1] Nanchang Inst Technol, Dept Sci, Nanchang 330099, Jiangxi, Peoples R China

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A | 2021年 / 95卷 / 09期

基金：

中国国家自然科学基金;

关键词：

self-assembly; temperature regulation; structural transition; scanning tunneling microscopy; TOTAL-ENERGY CALCULATIONS; TRIMESIC ACID; SOLID INTERFACE; 2D; CU(111);

D O I：

10.1134/S0036024421090247

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of temperature on the transformations of hydrogen-bonded structures of trimesic acid (TMA) and p-terphenyl-3,5,3'',5''-tetracarboxylic acid (TPTC) has been investigated at the nonanoic acid/highly oriented pyrolytic graphite (HOPG) interface by scanning tunneling microscopy (STM). STM observations show that TMA assembly based on temperature modulations underwent phase transitions from a chicken-wire (25 degrees C) to a flower (60 degrees C) and further to a guest-host flower structure. Similarly, TPTC network with five kinds of pores underwent change of structural conformation after annealing to 85 degrees C. This work provides a way toward controlled assembly directed by temperature and is beneficial for the understanding of both the assembling process and the underlying kinetics and thermodynamics for molecular nanostructures.

引用

页码：1871 / 1876

页数：6

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