Temperature-induced transitions of self-assembled phthalocyanine molecular nanoarrays at the solid-liquid interface: from randomness to order

被引：30

作者：

Hu, Fangyun ^{[1
,2
]}

Gong, Yunnan ^{[3
]}

Zhang, Xuemei ^{[1
]}

Xue, Jindong ^{[1
,2
]}

Liu, Bo ^{[2
]}

Lu, Tongbu ^{[3
]}

Deng, Ke ^{[1
]}

Duan, Wubiao ^{[2
]}

Zeng, Qingdao ^{[1
]}

Wang, Chen ^{[1
]}

机构：

[1] Chinese Acad Sci, Natl Ctr Nanosci & Technol, Key Lab Standardizat & Measurement Nanotechnol, Beijing 100190, Peoples R China

[2] Beijing Jiaotong Univ, Sch Sci, Dept Chem, Beijing 100044, Peoples R China

[3] Sun Yat Sen Univ, Sch Chem & Chem Engn, State Key Lab Optoelect Mat, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China

来源：

NANOSCALE | 2014年 / 6卷 / 08期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; BOTTOM-UP FABRICATION; SUPRAMOLECULAR NETWORKS; NANOPOROUS NETWORKS; PHASE-TRANSITIONS; MONO LAYERS; SURFACES; ARRAYS; STM; ARCHITECTURES;

D O I：

10.1039/c3nr06320h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A promising approach to create functional nanoarrays is supramolecular self-assembly at liquid-solid interfaces. In the present investigation, we report on the self-assembly of phthalocyanine arrays using triphenylene-2,6,10-tricarboxylic acid (H(3)TTCA) as a molecular nanotemplate. Five different metastable arrays are achieved in the study, including a thermodynamically stable configuration. Scanning tunneling microscopy (STM) measurements and density function theory (DFT) calculations are utilized to reveal the formation mechanism of the molecular nanoarrays. In general, the transformation process of nanoarrays is regulated by the synergies of a template effect and thermodynamic balance.

引用

页码：4243 / 4249

页数：7

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